Electrochemical Deposition and Formation Mechanism of Single-Crystalline Cu2O Octahedra on Aluminum

被引:17
作者
Du, Q. T. [1 ]
Tan, J. S. [1 ]
Wang, Q. T. [2 ]
Li, C. Y. [1 ]
Liu, X. H. [1 ]
Cai, R. S. [1 ]
Ding, Y. H. [1 ]
Wang, Y. Q. [1 ]
机构
[1] Qingdao Univ, Cultivat Base State Key Lab, Qingdao 266071, Peoples R China
[2] Qingdao Univ, Coll Phys Sci, Qingdao 266071, Peoples R China
关键词
SHAPE EVOLUTION; SIZE; GOLD; NANOCRYSTALS; NANOCUBES; TEMPLATE;
D O I
10.1155/2012/406162
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A simple electrochemical deposition was developed to synthesize the cuprous oxide (Cu2O) octahedra on aluminum foils. The average edge length of the octahedra is about 300 nm. The chemical composition of the octahedra was determined using energy dispersive X-ray spectroscopy and electron energy-loss spectroscopy. The microstructure of the octahedra was investigated using transmission electron microscopy. The formation mechanism of the octahedra is proposed.
引用
收藏
页数:8
相关论文
共 29 条
[1]   Formation of colloidal CuO nanocrystallites and their spherical aggregation and reductive transformation to hollow CU2O nanospheres [J].
Chang, Y ;
Teo, JJ ;
Zeng, HC .
LANGMUIR, 2005, 21 (03) :1074-1079
[2]   Cu2O:: Electrodeposition and characterization [J].
de Jongh, PE ;
Vanmaekelbergh, D ;
Kelly, JJ .
CHEMISTRY OF MATERIALS, 1999, 11 (12) :3512-3517
[3]   Nonvolatile memory and programmable logic from molecule-gated nanowires [J].
Duan, XF ;
Huang, Y ;
Lieber, CM .
NANO LETTERS, 2002, 2 (05) :487-490
[4]   Is the template of self-colloidal assemblies the only factor that controls nanocrystal shapes? [J].
Filankembo, A ;
Pileni, MP .
JOURNAL OF PHYSICAL CHEMISTRY B, 2000, 104 (25) :5865-5868
[5]   TEMPLATE-SYNTHESIZED NANOSCOPIC GOLD PARTICLES - OPTICAL-SPECTRA AND THE EFFECTS OF PARTICLE-SIZE AND SHAPE [J].
FOSS, CA ;
HORNYAK, GL ;
STOCKERT, JA ;
MARTIN, CR .
JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (11) :2963-2971
[6]   Electrochemical deposition of copper(I) oxide films [J].
Golden, TD ;
Shumsky, MG ;
Zhou, YC ;
VanderWerf, RA ;
VanLeeuwen, RA ;
Switzer, JA .
CHEMISTRY OF MATERIALS, 1996, 8 (10) :2499-2504
[7]   Solution-phase synthesis of Cu2O nanocubes [J].
Gou, LF ;
Murphy, CJ .
NANO LETTERS, 2003, 3 (02) :231-234
[8]   Size-controlled preparation of Cu2O octahedron nanocrystals and studies on their optical absorption [J].
He, P ;
Shen, XH ;
Gao, HC .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2005, 284 (02) :510-515
[9]   Wet chemical synthesis of high aspect ratio cylindrical gold nanorods [J].
Jana, NR ;
Gearheart, L ;
Murphy, CJ .
JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (19) :4065-4067
[10]   Photoinduced conversion of silver nanospheres to nanoprisms [J].
Jin, RC ;
Cao, YW ;
Mirkin, CA ;
Kelly, KL ;
Schatz, GC ;
Zheng, JG .
SCIENCE, 2001, 294 (5548) :1901-1903