Rh(I)-catalyzed ring-closing reaction of allenynes: selective construction of cycloheptene, bicyclo[5.3.0]decadienone, and bicyclo[5.2.0]nonene frameworks

被引：58

作者：

Mukai, C ^{[1
]}

Inagaki, F ^{[1
]}

Yoshida, T ^{[1
]}

Kitagaki, S ^{[1
]}

机构：

[1] Kanazawa Univ, Fac Pharmaceut Sci, Kanazawa, Ishikawa 9200934, Japan

来源：

TETRAHEDRON LETTERS | 2004年 / 45卷 / 21期

关键词：

Pauson-Khand reaction; cycloisomerization bicyclo[5.3.0]decane; bicyclo[5.2.0]nonane; allenyne electrocyclic reaction;

D O I：

10.1016/j.tetlet.2004.03.160

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Highly selective formation of cycloheptene, bicyclo[5.3.0]decadienone, and bicyclo[5.2.0]nonene skeletons from tri- and tetrasubstituted allenynes has been achieved via a Rh(I)-catalyzed ring-closing reaction and proper choice of substrate and/or reaction conditions. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：4117 / 4121

页数：5

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