Progress in the synthesis of carbon nanotube- and nanofiber-supported Pt electrocatalysts for PEM fuel cell catalysis

被引:351
作者
Lee, K
Zhang, JJ [1 ]
Wang, HJ
Wilkinson, DP
机构
[1] Natl Res Council Canada, Inst Fuel Cell Innovat, Vancouver, BC V6T 1W5, Canada
[2] Univ British Columbia, Dept Chem & Biol Chem, Vancouver, BC V6T 1Z4, Canada
关键词
carbon nanofiber; carbon nanotube; catalyst supports; electrocatalyst; oxygen electroreduction; PEM fuel cells; synthesis;
D O I
10.1007/s10800-006-9120-4
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
This paper reviews the literature on the synthesis of carbon nanotube- and nanofiber-supported Pt electrocatalysts for proton exchange membrane (PEM) fuel cell catalyst loading reduction through the improvement of catalyst utilization and activity, especially focusing on cathode nano-electrocatalyst preparation methods. The features of each synthetic method were also discussed based on the morphology of the synthesized catalysts. It is clear that synthesis methods play an important role in catalyst morphology, Pt utilization and catalytic activity. Though some remarkable progress has been made in nanotube- and nanofiber-supported Pt catalyst preparation techniques, the real breakthroughs have not yet been made in terms of cost-effectiveness, catalytic activity, durability and chemical/electrochemical stability. In order to make such electrocatalysts commercially feasible, cost-effective and innovative, catalyst synthesis methods are needed for Pt loading reduction and performance optimization.
引用
收藏
页码:507 / 522
页数:16
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