New and improved methods for the conversion of nitroalkanes into geminal chloronitroso compounds

被引：5
作者：
Bou-Moreno, Rafael [1 ]
Luengo-Arratta, Sandra [1 ]
Pons, Valerie [1 ]
Motherwell, William B. [1 ]
机构：
[1] UCL, Dept Chem, London WC1H 0AJ, England
来源：
CANADIAN JOURNAL OF CHEMISTRY | 2013年 / 91卷 / 01期
关键词：
geminal chloronitroso; silyl nitronate; DIELS-ALDER REACTION; C-NITROSO COMPOUNDS; ELECTROPHILIC AMINATION; TROPANE ALKALOIDS; HYDROXAMIC ACIDS; EFFICIENT METHOD; SYNTHETIC ROUTE; OXIMES; OXIDATION; CHLORINATION;
D O I：
10.1139/v2012-083
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The scope and limitations of a new method for the preparation of geminal chloronitroso compounds involving treatment of a nitronate anion with oxalyl chloride are described in full, and a milder, high yielding, and more chemoselective variant using the derived silyl nitronate is presented.
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页码：6 / 12
页数：7
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