Copper-Catalyzed Dehydrogenative Coupling of Arenes with Alcohols

被引：83

作者：

Bhadra, Sukalyan ^{[1
]}

Matheis, Christian ^{[1
]}

Katayev, Dmitry ^{[1
]}

Goossen, Lukas J. ^{[1
]}

机构：

[1] Tech Univ Kaiserslautern, FB Chem Organ Chem, D-67663 Kaiserslautern, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 35期

关键词：

CH activation; CO coupling; copper; dehydrogenative cross-coupling; homogeneous catalysis; C-H BOND; FREE SILVER(I) ALKOXIDE; ORTHO-ARYLATION; OXIDATIVE FUNCTIONALIZATION; INTERMOLECULAR DEHYDRATION; SODIUM PERSULFATE; SINGLE-ELECTRON; DIRECTING GROUP; ARYL ETHERS; ACTIVATION;

D O I：

10.1002/anie.201303702

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

What a couple! Arenes functionalized with donating groups undergo oxidative dehydrogenative coupling with alcohols in the presence of a copper/silver catalyst system. This intermolecular C-H alkoxylation provides a convenient synthetic route to the important class of aryl ethers. The catalyst system also allows the alkoxylation of benzylic C-H groups with formation of benzyl alkyl ethers. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：9279 / 9283

页数：5

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