Actinide-mediated cyclization of 1,2,4,5-tetracyanobenzene: Synthesis and characterization of self-assembled trinuclear thorium and uranium macrocycles

被引：39
|
作者：
Kiplinger, JL [1 ]
Pool, JA [1 ]
Schelter, EJ [1 ]
Thompson, JD [1 ]
Scott, BL [1 ]
Morris, DE [1 ]
机构：
[1] Los Alamos Natl Lab, Los Alamos, NM 87545 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 13期
关键词：
metallomacrocycles; self-assembly; tetracyanobenzene; thorium; uranium;
D O I：
10.1002/anie.200504306
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Figure Presented) Heavy metal triangles: A class of actinide metallomacrocycles has been prepared in which three (C5Me 5)2An (An = Th, U) fragments are coordinated by three 5,6-dicyano-1-methyl-3-(N-methylamino)-isoindolyl bridging ligands (N blue). The tetravalent actinide centers form a triangular array in the products obtained through an unprecedented actinide-mediated cyclization of 1,2,4,5- tetracyanobenzene and subsequent self-assembly. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：2036 / 2041
页数：6
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