A luminescent iridium(III) cyclometallated complex immobilized in a polymeric matrix as a solid-state oxygen sensor

被引：62

作者：

DiMarco, G ^{[1
]}

Lanza, M ^{[1
]}

Pieruccini, M ^{[1
]}

Campagna, S ^{[1
]}

机构：

[1] UNIV MESSINA,DIPARTIMENTO CHIM INORGAN,I-98166 MESSINA,ITALY

来源：

ADVANCED MATERIALS | 1996年 / 8卷 / 07期

关键词：

D O I：

10.1002/adma.19960080709

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Communication: In luminescence-based oxygen sensors the active luminescent species is usually a transition metal complex immobilized in a polymeric matrix-in most cases a ruthenium(II) polypyridine complex. In an attempt to overcome some of the disadvantages of these systems, a polymer-immobilized iridium(III) complex has been prepared and used for the first time as the active species in such a sensor. The luminescence properties of this system are described and its drawbacks with regard to sensors technology discussed.

引用

页码：576 / &

页数：6

共 29 条

[1] LUMINESCENT METAL-COMPLEXES .5. LUMINESCENCE PROPERTIES OF RING-SUBSTITUTED 1,10-PHENANTHROLINE TRIS-COMPLEXES OF RUTHENIUM(II) [J].

ALFORD, PC ;

COOK, MJ ;

LEWIS, AP ;

MCAULIFFE, GSG ;

SKARDA, V ;

THOMSON, AJ ;

GLASPER, JL ;

ROBBINS, DJ .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1985, (05) :705-709

[2]

[Anonymous], PHOTOCHEMISTRY PHOTO

[3] DETERMINATION OF OXYGEN CONCENTRATIONS BY LUMINESCENCE QUENCHING OF A POLYMER-IMMOBILIZED TRANSITION-METAL COMPLEX [J].

BACON, JR ;

DEMAS, JN .

ANALYTICAL CHEMISTRY, 1987, 59 (23) :2780-2785

[4]

Balzani V.S. F., 1991, Supramolecular Photochemistry

[5]

BISSELL RA, 1993, TOP CURR CHEM, V168, P223

[6] ABSORPTION-SPECTRA, LUMINESCENCE PROPERTIES, AND ELECTROCHEMICAL-BEHAVIOR OF CYCLOMETALATED IRIDIUM(III) AND RHODIUM(III) COMPLEXES WITH A BIS(PYRIDYL)TRIAZOLE LIGAND [J].

CALOGERO, G ;

GIUFFRIDA, G ;

SERRONI, S ;

RICEVUTO, V ;

CAMPAGNA, S .

INORGANIC CHEMISTRY, 1995, 34 (03) :541-545

[7] PHOTOPHYSICS OF RU(II)-POLYPYRIDINE AND OS(II)-POLYPYRIDINE COMPLEXES IN POLY(ETHYLENEOXIDE) MATRICES [J].

CAMPAGNA, S ;

BARTOLOTTA, A ;

DIMARCO, G .

CHEMICAL PHYSICS LETTERS, 1993, 206 (1-4) :30-36

[8]

CZARNIK AW, 1992, ACS S SER, V538

[9] A MOLECULAR PHOTOIONIC AND GATE BASED ON FLUORESCENT SIGNALING [J].

DE SILVA, AP ;

GUNARATNE, HQN ;

MCCOY, CP .

NATURE, 1993, 364 (6432) :42-44

[10] A NEW KIND OF OXYGEN-SENSITIVE TRANSDUCER BASED ON AN IMMOBILIZED METALLOORGANIC COMPOUND [J].

DELBIANCO, A ;

BALDINI, F ;

BACCI, M ;

KLIMANT, I ;

WOLFBEIS, OS .

SENSORS AND ACTUATORS B-CHEMICAL, 1993, 11 (1-3) :347-350

← 1 2 3 →