Study of the synthesis and properties of the ternary complexes of rare earths with mandelic acid and 1,10-phenanthroline

被引：4

作者：

Ren, YP ^{[1
]}

Yan, GL ^{[1
]}

Zhang, L ^{[1
]}

Yu, KY ^{[1
]}

Wang, LF ^{[1
]}

Wu, JG ^{[1
]}

机构：

[1] LANZHOU UNIV,DEPT CHEM,LANZHOU 730000,PEOPLES R CHINA

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 1996年 / 26卷 / 02期

关键词：

D O I：

10.1080/00945719608004265

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Fourteen ternary complexes of rare earths with mandelic acid (MAH) and 1,10-phenanthroline (phen) have been prepared in aqueous solution. The composition of the ternary complexes has been determined as RE(MA)(3) . phen . nH(2)O (RE = La, Ce, Pr, Nd, n = 0; RE = Sm, n 1/2; RE Eu, Gd, Dy-Lu, Y, n = 1) by elemental and chemical analyses, Their solubility in different solvents and molar conductances were measured. The structures and properties of the ternary complexes were investigated using IR, TGA, X-ray powder diffraction and UV. The bonding character of the complexes are also discussed.

引用

页码：293 / 303

页数：11

共 50 条

[21] Synthesis and characterization of transition metal ternary complexes of glyoxylic acid thiosemicarbazone and 1,10-phenanthroline
Liu, SX
Tian, JL
Gao, EQ
Bi, SW
Li, YT
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1996, 26 (09): : 1447 - 1454
[22] IR and Raman spectra of ternary solid complexes of rare earth with α-naphthoic acid and 1,10-phenanthroline
Yang, H
Wang, ZM
Yang, HF
Yu, XB
SPECTROSCOPY AND SPECTRAL ANALYSIS, 2003, 23 (03) : 522 - 524
[23] ON TERNARY COMPLEXES OF THE IRON(III) ION WITH 1,10-PHENANTHROLINE AND KOJIK ACID
KOCH, S
ACKERMANN, G
ZEITSCHRIFT FUR CHEMIE, 1990, 30 (01): : 33 - 33
[24] Synthesis and magnetic properties of poly(amic acid) complexes containing 1,10-phenanthroline
Zheng, Renhua
Jiang, Huajiang
Guo, Haichang
Sun, Weilin
E-POLYMERS, 2011,
[25] Synthesis and Study of Complexes of Lanthanide Caproates with 1,10-Phenanthroline
Korovin, S. S.
Lebedeva, E. N.
Tkachenko, O. Yu.
Zaitseva, M. G.
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 1999, 44 (05) : 694 - 701
[26] Synthesis and spectroscopic properties of rare earth complexes with o-phthalate and 1,10-phenanthroline
Wang, XG
Wu, HY
Xie, DT
Weng, SF
Wu, JG
SPECTROSCOPY AND SPECTRAL ANALYSIS, 2001, 21 (06) : 807 - 810
[27] Synthesis and spectroscopic properties of rare earth complexes with o-phthalate and 1,10-phenanthroline
Wang, Xi-Gui
Wu, Hong-Ying
Xie, Da-Tao
Weng, Shi-Fu
Wu, Jin-Guang
Guang Pu Xue Yu Guang Pu Fen Xi/Spectroscopy and Spectral Analysis, 2001, 21 (06):
[28] The synthesis, luminescence and energy transfer of the binary and ternary complexes of rare earth with aminobenzoic acids and 1,10-phenanthroline
Yan, B
Zhang, HJ
Ni, JZ
CHINESE CHEMICAL LETTERS, 1997, 8 (04) : 353 - 356
[29] The Synthesis, Luminescence and Energy Transfer of the Binary and Ternary Complexes of Rare Earth with Aminobenzoic Acids and 1,10-Phenanthroline
Bing YAN
Hong Jie ZHANG and Jia Zuan NI(Labortory of Rare Earth Chemistry and Physics
Chinese Chemical Letters, 1997, (04) : 353 - 356
[30] Synthesis, structure and nuclease properties of several ternary copper(II) peptide complexes with 1,10-phenanthroline
García-Raso, A
Fiol, JJ
Adrover, B
Moreno, V
Mata, I
Espinosa, E
Molins, E
JOURNAL OF INORGANIC BIOCHEMISTRY, 2003, 95 (2-3) : 77 - 86

← 1 2 3 4 5 →