Enhancing effects on the catalytic performance during the preparation of nickel supported lanthanum-alumina catalyst for the catalytic carbon dioxide dry reforming of methane

被引:3
作者
Song, Sang-Hoon [1 ,2 ]
Park, Jung Eun [3 ]
Chang, Tae-Sun [1 ]
Suh, Jeong-Kwon [1 ]
机构
[1] Korea Res Inst Chem Technol, Res Ctr Environm Resources & Proc, Taejon 305343, South Korea
[2] Chungbuk Natl Univ, Dept Chem Engn, Chungbuk 361763, South Korea
[3] Ajou Univ, Dept Chem Engn & Mat Engn, Suwon 443749, South Korea
关键词
Lanthanum; La/Al ratio; Dry-reforming; Carbon dioxide; STEAM; LA2O3; ADDITIVES; CH4;
D O I
10.1007/s11144-012-0484-7
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The influence of the composition and calcination temperature on nickel-lanthanum-alumina catalysts was specifically studied for the catalytic carbon dioxide dry reforming of methane (CDR) in this paper. The addition of lanthanum promoter to Ni-Al resulted in high activity and stability for the CDR process. The calcined catalyst showed a maximum activity at the temperature of 873 K. The catalysts prepared by the co-precipitation method had higher activity than those prepared by the impregnation method. The characterization was performed by using BET, ICP-AES, XRD, IR, EPMA and XPS.
引用
收藏
页码:161 / 171
页数:11
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