Crystal structure and Hirshfeld surface analysis of 4-{2,2-dichloro-1 -[(E)-2-(4-methylphenyl)diazen-1-yl]ethenyl}-N,N-dimethylanmne

被引：4
|
作者：
Ozkaraca, Kadriye [1 ]
Akkurt, Mehmet [2 ]
Shikhaliyev, Namiq Q. [3 ]
Askerova, Ulviyya F. [3 ]
Suleymanova, Gulnar T. [3 ]
Mammadova, Gunay Z. [3 ]
Mlowe, Sixberth [4 ]
机构：
[1] Erciyes Univ, Inst Nat & Appl Sci, TR-38039 Kayseri, Turkey
[2] Erciyes Univ, Fac Sci, Dept Phys, TR-38039 Kayseri, Turkey
[3] Baku State Univ, Organ Chem Dept, Z Khalilov Str 23, AZ-1148 Baku, Azerbaijan
[4] Univ Dar Es Salaam, Coll Educ, Dept Chem, POB 2329, Dar Es Salaam, Tanzania
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2020年 / 76卷
关键词：
crystal structure; Hirshfeld surface analysis; non-covalent interactions; halogen and H-atom contacts;
D O I：
10.1107/S2056989020007744
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the tile compound, C17H17Cl2N3, the dihedral angle between the benzene rings is 62.73 (9)degrees. In the crystal, there are no classical hydrogen bonds. Molecules are linked by a pair of C-Cl center dot center dot center dot pi interactions, forming an inversion dimer. A short intermolecular HL center dot center dot center dot HL contact [Cl center dot center dot center dot Cl = 3.2555 (9) angstrom] links the dimers, forming a ribbon along the c-axis direction. The Hirshfeld surface analysis and two-dimensional fingerprint plots reveal that the most important contributions for the crystal packing are from H center dot center dot center dot H (45.4%), Cl center dot center dot center dot H/H center dot center dot center dot Cl (21.0%) and C center dot center dot center dot H/H center dot center dot center dot C (19.0%) contacts.
引用
收藏
页码：1122 / +
页数：9
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