Olefin epoxidation catalysed by Schiff-base complexes of Mn and Ni in heterogenised-homogeneous systems

被引：79

作者：

Chatterjee, D ^{[1
]}

Mitra, A ^{[1
]}

机构：

[1] Cent Mech Engn Res Inst, Chem Sect, Durgapur 713209, India

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1999年 / 144卷 / 02期

关键词：

olefin epoxidation; salen complexes of Mn and Ni; heterogenised-homogeneous catalysis; zeolite; montomorillonite;

D O I：

10.1016/S1381-1169(99)00093-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

M(salen) complexes (M = Mn(III), Ni(II); salen = bis-(salicyldene)ethylenediamine) have been encapsulated in zeolite Y and characterised. Mn(salen)(+) complex was also anchored in montmorillonite clay and characterised. Epoxidation of olefins, viz. cyclohexene, cyclooctene and 1-hexene with terminal oxidants (NaOCl, KHSO5) was carried out with the anchored catalyst complexes and found that the epoxidation of Linear olefin (1-hexene) is selectively facile than cyclic olefins. Experimental results are compared with those reported for M(salen) complexes catalysed olefin epoxidation in homogeneous and heterogenised-homogeneous catalytic conditions. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：363 / 367

页数：5