Deoxygenation of Biomass-Derived Feedstocks: Oxorhenium-Catalyzed Deoxydehydration of Sugars and Sugar Alcohols

被引：220

作者：

Shiramizu, Mika ^{[1
]}

Toste, F. Dean ^{[1
]}

机构：

[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 32期

关键词：

biomass; deoxydehydration; deoxygenation; rhenium; sustainable chemistry; ENANTIOSELECTIVE REDUCTION; RHENIUM; CHEMICALS; CONVERSION; PYROLYSIS; ALKENES; ROUTES; DIOLS; BOND; OIL;

D O I：

10.1002/anie.201203877

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Turn sugar into oil: The deoxygenation reaction of sugar moieties is important for the conversion of biomass into chemicals and fuels. The methyltrioxorhenium-catalyzed deoxydehydration reaction was successfully applied to this purpose using another alcohol as solvent/reductant. The reaction was highly stereospecific, affording linear polyene products from C 4-C6 sugar alcohols and aromatic compounds from C 4-C6 sugars. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：8082 / 8086

页数：5

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