Free-standing heterogeneous hybrid papers based on mesoporous γ-MnO2 particles and carbon nanotubes for lithium-ion battery anodes

被引：52
作者：
Yun, Young Soo [1 ]
Kim, Jung Min [2 ]
Park, Hyun Ho [1 ]
Lee, Jaehoon [1 ]
Huh, Yun Suk [2 ]
Jin, Hyoung-Joon [1 ]
机构：
[1] Inha Univ, Dept Polymer Sci & Engn, Inchon 402751, South Korea
[2] KBSI, Div Mat Sci, Taejon 305333, South Korea
来源：
JOURNAL OF POWER SOURCES | 2013年 / 244卷
基金：
新加坡国家研究基金会;
关键词：
Hybrid; Anode; Lithium-ion battery; Carbon nanotube; Manganese oxide; NANOSTRUCTURED MATERIALS; MANGANESE OXIDE; HIGH-CAPACITY; ENERGY-CONVERSION; STORAGE DEVICES; ELECTRODES; ROUTE; ROPES; FILMS;
D O I：
10.1016/j.jpowsour.2012.11.056
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Free-standing heterogeneous hybrid papers based on mesoporous gamma-MnO2 particles and acid-treated single-walled carbon nanotubes (a-SWCNTs) for lithium-ion battery anodes are successfully prepared by simple vacuum filtration. The mesoporous gamma-MnO2 particles with high surface areas are well dispersed throughout these anodes by being bound in nanoporous a-SWCNT networks. Furthermore, these anodes exhibit a high electrical conductivity of 2.5 x 10(2) S cm(-1) with high flexibility, which makes them substrate- and binder-free. For 50 wt% mesoporous gamma-MnO2 particle-loaded anodes, a high reversible capacity of 934 mA h g(-1) (0.01-3.0 V) is maintained after 150 cycles. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码：747 / 751
页数：5
相关论文
共 36 条
[1]   Nanostructured materials for advanced energy conversion and storage devices [J].
Aricò, AS ;
Bruce, P ;
Scrosati, B ;
Tarascon, JM ;
Van Schalkwijk, W .
NATURE MATERIALS, 2005, 4 (05) :366-377
[2]   Carbon nanotubes - the route toward applications [J].
Baughman, RH ;
Zakhidov, AA ;
de Heer, WA .
SCIENCE, 2002, 297 (5582) :787-792
[3]   Carbon nanotube network modified carbon fibre paper for Li-ion batteries [J].
Chen, Jun ;
Wang, Jiao Zhao ;
Minett, Andrew I. ;
Liu, Yong ;
Lynam, Carol ;
Liu, Huakun ;
Wallace, Gordon G. .
ENERGY & ENVIRONMENTAL SCIENCE, 2009, 2 (04) :393-396
[4]   Flexible free-standing carbon nanotube films for model lithium-ion batteries [J].
Chew, Sau Yen ;
Ng, See How ;
Wang, Jiazhao ;
Novak, Petr ;
Krumeich, Frank ;
Chou, Shu Lei ;
Chen, Jun ;
Liu, Hua Kun .
CARBON, 2009, 47 (13) :2976-2983
[5]   High capacity and excellent cyclability of vanadium (IV) oxide in lithium battery applications [J].
Ding, Ning ;
Feng, Xuyong ;
Liu, Shuhua ;
Xu, Jing ;
Fang, Xin ;
Lieberwirth, Ingo ;
Chen, Chunhua .
ELECTROCHEMISTRY COMMUNICATIONS, 2009, 11 (03) :538-541
[6]   Carbon nanotube quantum resistors [J].
Frank, S ;
Poncharal, P ;
Wang, ZL ;
de Heer, WA .
SCIENCE, 1998, 280 (5370) :1744-1746
[7]   Nanostructured materials: Basic concepts and microstructure [J].
Gleiter, H .
ACTA MATERIALIA, 2000, 48 (01) :1-29
[8]   Nanostructured materials for electrochemical energy conversion and storage devices [J].
Guo, Yu-Guo ;
Hu, Jin-Song ;
Wan, Li-Jun .
ADVANCED MATERIALS, 2008, 20 (15) :2878-2887
[9]   Silicon-Carbon Nanotube Coaxial Sponge as Li-Ion Anodes with High Areal Capacity [J].
Hu, Liangbing ;
Wu, Hui ;
Gao, Yifan ;
Cao, Anyuan ;
Li, Hongbian ;
McDough, James ;
Xie, Xing ;
Zhou, Min ;
Cui, Yi .
ADVANCED ENERGY MATERIALS, 2011, 1 (04) :523-527
[10]   Thin, Flexible Secondary Li-Ion Paper Batteries [J].
Hu, Liangbing ;
Wu, Hui ;
La Mantia, Fabio ;
Yang, Yuan ;
Cui, Yi .
ACS NANO, 2010, 4 (10) :5843-5848
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