Reversible dynamic isomerism change in the solid state, from Bi4I16 clusters to BiI4 1D chains in L-cystine based hybrids: templating effect of cations in iodobismuthate network formation

被引：56

作者：

Bi, Wenhua ^{[1
]}

Mercier, Nicolas ^{[1
]}

机构：

[1] CNRS, UMR 6200, F-49045 Angers, France

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 44期

关键词：

D O I：

10.1039/b812588k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The dehydration of a iodobismuthate hybrid built up from Bi4I16 clusters and protonated L-cystine molecules involves an unprecedented reversible dynamic structural change in the solid state leading to 1D BiI4 chains and 1D helical molecular chains, highlighting the templating effect of cations in the formation of iodobismuthate network.

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页码：5743 / 5745

页数：3

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