Hybrid materials in the removal of diclofenac sodium from aqueous solutions: Batch and column studies

被引:24
作者
Tiwari, Diwakar [1 ]
Lalhriatpuia, C. [1 ]
Lee, Seung-Mok [2 ]
机构
[1] Mizoram Univ, Sch Phys Sci, Dept Chem, Aizawl 796004, India
[2] Catholic Kwandong Univ, Dept Environm Engn, Kangnung 210701, South Korea
关键词
Microporous; Diclofenac sodium; Micro-pollutants; Hybrid materials; Decontamination; AQUATIC ENVIRONMENT; ACTIVATED CARBON; ADVANCED OXIDATION; DRUG DICLOFENAC; WATER; ADSORPTION; PHARMACEUTICALS; DRINKING; SERICITE; CARBAMAZEPINE;
D O I
10.1016/j.jiec.2015.05.018
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Hybrid materials (AAS (Al-AMBA-sericite and AHS (Al-HDTMA-sericite)) was obtained and materials are characterized by XRD, SEM and IR analytical techniques. Hybrid materials were assessed for efficient removal of diclofenac from aqueous solutions. Increasing the diclofenac concentration (1.0 to 20.0 mg/L) and pH 2 to 7 favored greatly the removal of diclofenac by AAS and AHS. Background electrolyte concentrations from 0.0001 to 0.1 mol/LNaCI, insignificantly affected percent removal of diclofenac. The breakthrough results were fitted well to the Thomas equation and hence, loading capacity of diclofenac was found to be 0.561 and 1.056 mg/g for MS and AHS, respectively. (C) 2015 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:167 / 173
页数:7
相关论文
共 61 条
[1]   Fixed bed column study for the removal of crystal violet (C. I. Basic Violet 3) dye from aquatic environment by surfactant-modified alumina [J].
Adak, A ;
Bandyopadhyay, M ;
Pal, A .
DYES AND PIGMENTS, 2006, 69 (03) :245-251
[2]  
Al-Khateeb LA, 2014, J IND ENG CHEM, V20, P916
[3]   Removal of diclofenac sodium from aqueous solution by Isabel grape bagasse [J].
Antunes, Marjore ;
Esteves, Valdemar I. ;
Guegan, Regis ;
Crespo, Janaina S. ;
Fernandes, Andreia N. ;
Giovanela, Marcelo .
CHEMICAL ENGINEERING JOURNAL, 2012, 192 :114-121
[4]   X-ray absorption spectroscopic investigation of arsenite and arsenate adsorption at the aluminum oxide-water interface [J].
Arai, Y ;
Elzinga, EJ ;
Sparks, DL .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2001, 235 (01) :80-88
[5]   Diclofenac removal from water with ozone and activated carbon [J].
Beltran, Fernando J. ;
Pocostales, Pablo ;
Alvarez, Pedro ;
Oropesa, Ana L. .
JOURNAL OF HAZARDOUS MATERIALS, 2009, 163 (2-3) :768-776
[6]  
Bort R, 1999, J PHARMACOL EXP THER, V288, P65
[7]  
Chen Y.-G., 2014, J IND ENG CHEM
[8]   Selective removal of diclofenac from contaminated water using molecularly imprinted polymer microspheres [J].
Dai, Chao-meng ;
Geissen, Sven-Uwe ;
Zhang, Ya-lei ;
Zhang, Yong-jun ;
Zhou, Xue-fei .
ENVIRONMENTAL POLLUTION, 2011, 159 (06) :1660-1666
[9]   Fe0-based trimetallic systems for the removal of aqueous diclofenac: Mechanism and kinetics [J].
Ghauch, Antoine ;
Abou Assi, Hala ;
Baydoun, Habib ;
Tuqan, Al Muthanna ;
Bejjani, Alice .
CHEMICAL ENGINEERING JOURNAL, 2011, 172 (2-3) :1033-1044
[10]   Adsorption of As(III) from aqueous solutions by iron oxide-coated sand [J].
Gupta, VK ;
Saini, VK ;
Jain, N .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2005, 288 (01) :55-60