Coordination chemistry beyond Werner: interplay between hydrogen bonding and coordination

被引:82
|
作者
Reedijk, Jan [1 ,2 ]
机构
[1] Leiden Univ, Leiden Inst Chem, Gorlaeus Labs, NL-2300 RA Leiden, Netherlands
[2] King Saud Univ, Coll Sci, Dept Chem, Riyadh 11451, Saudi Arabia
关键词
LIGAND-FIELD CALCULATIONS; RAY CRYSTAL-STRUCTURE; SPIN FE(II) COMPOUNDS; NONHEME IRON SITES; MAGNETIC-PROPERTIES; AQUA-LIGANDS; WATSON-CRICK; METAL-IONS; BASE-PAIR; COMPLEXES;
D O I
10.1039/c2cs35239g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A tutorial review is presented dealing with the role of hydrogen bonding in coordination compounds. Examples are given for important intramolecular hydrogen bonding, and stabilising unusual coordination geometries, or reactive species. Also examples are discussed for intermolecular H-bonds between coordination entities and anions, and for stabilising crystal lattices, like in coordination polymers.
引用
收藏
页码:1776 / 1783
页数:8
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