Synthesis of Chiral Allylic Thioesters: Enantio- and Regioselective Iridium-Catalyzed Allylations of KSAc

被引：12

作者：

Gao, Ning ^{[1
]}

Zhao, Xiaoming ^{[1
,2
]}

机构：

[1] Tongji Univ, Dept Chem, Shanghai 200092, Peoples R China

[2] Shanghai Inst Organ Chem, Key Lab Fluorine Chem, Shanghai 200032, Peoples R China

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2013年 / 2013卷 / 13期

基金：

中国国家自然科学基金;

关键词：

Asymmetric catalysis; Enantioselectivity; Allylic compounds; Iridium; ENANTIOSELECTIVE SYNTHESIS; ASYMMETRIC-SYNTHESIS; KINETIC RESOLUTION; SUBSTITUTION; THIOLS; AMINATION; SULFIDES; ALCOHOLS; ETHERIFICATION; CONVERSION;

D O I：

10.1002/ejoc.201201640

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Chiral allylic thioesters were synthesized through a direct iridium-catalyzed asymmetric allylation of KSAc in the presence of KOAc. This strategy provided branched allylic thioesters in good yields with the high levels of enantioselectivity.

引用

页码：2708 / 2714

页数：7

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