Research and development of the preparation method of thermally stable polymer "MSP"

被引：0

作者：

Itoh, M ^{[1
]}

机构：

[1] Mitsui Chem Inc, Organ Performance Mat Lab, Sakae Ku, Yokohama, Kanagawa 2478567, Japan

来源：

JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN | 1999年 / 57卷 / 05期

关键词：

ploy[(phenylsilylene)ethynylene-1,3-phenyleneethynylene; silicon containing polymer; heat-resistant; dehydrogenative coupling polymerization; phenylsilane; diethynylbenzene; bench test; magnesia; solid base catalyst;

D O I：

10.5059/yukigoseikyokaishi.57.442

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new highly heat-resistant polymer containing silicon, poly [(phenylsilylene)ethynylene-1,3-phenyleneethynylene] (MSP), was prepared by dehydrogenative coupling polymerization between phenylsilane and 1,3-diethynylbenzene in the presence of magnesia and other base catalysts. The research and development of preparation process of MSP are described, and the preparation flow chart in a bench test using a magnesia catalyst are shown. The properties and some applications of MSP are also reported.

引用

页码：442 / 449

页数：8

共 15 条

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