Synthesis, crystal structure and electrochemical properties of copper(II) complex [Cu(PTA)(phen)2]•(PTA)(H2O)4

被引：0
作者：
Li, W
Li, CH
Yang, YQ
Kuang, DZ [1 ]
Chen, ZM
Xu, WJ
Chen, MS
机构：
[1] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China
[2] Hunan Univ, Coll Chem & Chem Engn, Changsha 410082, Peoples R China
[3] Hengyang Normal Univ, Dept Chem Engn, Hengyang 421008, Hunan, Peoples R China
来源：
CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2006年 / 22卷 / 01期
关键词：
copper(II)) complex; crystal structure; electrochemical property;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The title complex has been synthesized by using terephthalic acid (PTA), 1,10-phenanthroline (phen) and copper monohydrate. It crystallizes In monoclinic space group C2/c with a=2.9590(2) nm, b=1.4664(10) nm, c=1.7643(12) nm, beta=105.593(11)degrees, V=7.372(9) nm(3), D-c=1.489 g(.)cm(-3), Z=8, F(000)=3416, R-1=0.0436, wR(2)= 0.1519. The crystal structure shows that the copper atom is coordinated with four nitrogen atoms from two phens and one oxygen atom from one tereplithalic acid, forming a distorted square-pyramid coordination geometry. The cyclic voltametric behavior of the complex is also reported. CCDC: 277047.
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页码：101 / 105
页数：5
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