Synthesis and radical polymerization behavior of bifunctional vinyl monomer derived from N-vinylacetamide and p-chloromethylstyrene

被引：7

作者：

Iwamura, T ^{[1
]}

Nakagawa, T ^{[1
]}

Endo, T ^{[1
]}

机构：

[1] Tokyo Inst Technol, Res Lab Resources Utilizat, Midori Ku, Yokohama, Kanagawa 2268503, Japan

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2006年 / 44卷 / 08期

关键词：

chemical modification; crosslinking reaction; N-vinylacetamide; p-chloromethylstyrene; radical polymerization;

D O I：

10.1002/pola.21381

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The radical polymerization of N-(p-vinylbenzyl)-N-vinylacetamide (1) prepared by the reaction of N-vinylacetamide with p-chloromethyl styrene was carried out by using radical initiators such as AIBN or BPO in benzene, chlorobenzene, or bulk. As a result, poly 1 was successfully isolated by dialysis (yield, 10-36%). The crosslinking reaction of poly 1 was carried out at 60-100 degrees C for 8 h. By using a radical initiator such as AIBN or BPO (3 mol %), the crosslinking reaction proceeded (yield, 63-79%). Moreover, the crosslinking reaction of poly 1 proceeded at 100 degrees C without a radical initiator in 50% yield. (c) 2006 Wiley Periodicals, Inc.

引用

页码：2714 / 2723

页数：10

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