Shape memory of hydrogen-bonded polymer network/poly(ethylene glycol) complexes

被引：103

作者：

Liu, GQ ^{[1
]}

Ding, XB ^{[1
]}

Cao, YP ^{[1
]}

Zheng, ZH ^{[1
]}

Peng, YX ^{[1
]}

机构：

[1] Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China

来源：

MACROMOLECULES | 2004年 / 37卷 / 06期

关键词：

D O I：

10.1021/ma035717w

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Because of a large difference in storage modulus below and above the glass transition temperature, poly(acrylic acid-co-methyl methacrylate)/poly(ethylene glycol) (P(AA-co-MMA)/PEG) complexes show shape memory properties with a recovery ratio of nearly reach 99%. Before the shape memory testing, it was necessary to determine the conformational changes of the P(AA-co-MMA) gel induced by complexation with linear PEG. It was found that both the concentration and molecular weight of PEG have a strong effect on the complexation with P(AA-co-MMA) gel. In such a system the minimum molecular weight of PEG required for the complex formation lowers to 1000.

引用

页码：2228 / 2232

页数：5

共 25 条

[1]

AUBIN M, 1984, MAKROMOL CHEM-RAPID, V5, P419

[2]

Bekturov EA, 2000, MACROMOL CHEM PHYSIC, V201, P1031, DOI 10.1002/1521-3935(20000601)201:10<1031::AID-MACP1031>3.0.CO

[3]

2-6

[4] Complex of polyelectrolyte network with surfactant as novel shape memory networks [J].

Guan, Y ;

Cao, YP ;

Peng, YX ;

Xu, J ;

Chen, ASC .

CHEMICAL COMMUNICATIONS, 2001, (17) :1694-1695

[5] INTERPOLYMER COMPLEX BETWEEN POLY(ETHYLENE OXIDE) AND POLY(CARBOXYLIC ACID) [J].

IKAWA, T ;

ABE, K ;

HONDA, K ;

TSUCHIDA, E .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1975, 13 (07) :1505-1514

[6] Conformational transitions in poly(methacrylic acid) gel/poly(ethylene glycol) complexes. Effect of the gel cross-linking density [J].

Karybiants, NS ;

Philippova, OE ;

Starodoubtsev, SG ;

Khokhlov, AR .

MACROMOLECULAR CHEMISTRY AND PHYSICS, 1996, 197 (08) :2373-2378

[7] Polyurethanes having shape memory effects [J].

Kim, BK ;

Lee, SY ;

Xu, M .

POLYMER, 1996, 37 (26) :5781-5793

[8] Miscibility and hydrogen bonding in blends of poly(vinylphenol-co-methyl methacrylate) with poly(ethylene oxide) [J].

Kuo, SW ;

Chang, FC .

MACROMOLECULES, 2001, 34 (12) :4089-4097

[9] Structure and thermomechanical properties of polyurethane block copolymers with shape memory effect [J].

Lee, BS ;

Chun, BC ;

Chung, YC ;

Sul, KI ;

Cho, JW .

MACROMOLECULES, 2001, 34 (18) :6431-6437

[10] STRENGTHENING EFFECT ON SHAPE RECOVERY CHARACTERISTIC OF THE EQUIATOMIC TINI ALLOY [J].

LIN, HC ;

WU, SK .

SCRIPTA METALLURGICA ET MATERIALIA, 1992, 26 (01) :59-62

← 1 2 3 →