Palladacycle-Catalyzed Carbonylation of Aryl Iodides or Bromides with Aryl Formates

被引：12

作者：

Chen, Guangwei ^{[1
]}

Leng, Yuting ^{[1
]}

Yang, Fan ^{[1
]}

Wang, Shiwei ^{[2
]}

Wu, Yangjie ^{[1
]}

机构：

[1] Zhengzhou Univ, Coll Chem & Mol Engn, Key Lab Appl Chem Henan Univ, Key Lab Chem Biol & Organ Chem Henan Prov, Zhengzhou 450052, Henan, Peoples R China

[2] Zhengzhou Univ, Coll Mech & Engn Sci, Zhengzhou 450001, Henan, Peoples R China

来源：

CHINESE JOURNAL OF CHEMISTRY | 2013年 / 31卷 / 12期

基金：

中国国家自然科学基金;

关键词：

carbonylation; aryl formates; palladacycle; catalysis; AROMATIC ESTERIFICATION; CARBOXYLIC-ACIDS; PALLADIUM; ALKOXYCARBONYLATION; CHLORIDES; HALIDES; ALDEHYDES; DERIVATIVES; COMPLEXES; OXIDATION;

D O I：

10.1002/cjoc.201300675

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An efficient palladacycle-catalyzed aromatic carbonylation reaction of aryl formates with aryl iodides or bromides has been developed. Commercially available and easily prepared aryl formates were employed as carbonyl sources without the use of external carbon monoxide. The present catalytic system shows broad functional group tolerance and affords aryl benzoate derivatives in good to excellent yields.

引用

页码：1488 / 1494

页数：7

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