Spectroscopy of metal ion complexes: Gas-phase models for solvation

被引：251
作者：
Duncan, MA
机构：
[1] Department of Chemistry, University of Georgia, Athens
来源：
ANNUAL REVIEW OF PHYSICAL CHEMISTRY | 1997年 / 48卷
关键词：
metal ions; metal complexes; electronic spectroscopy; clusters;
D O I：
10.1146/annurev.physchem.48.1.69
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Weakly bound metal ion complexes are produced in molecular beams and studied with mass-selected laser photodissociation spectroscopy. The metal ions Mg+ and Ca+ are the focus of these studies because they have a single valence electron and strong atomic resonance lines in convenient wavelength regions. Weakly bound complexes of these ions with rare-gas atoms and small molecules are prepared with laser vaporization ina pulsed nozzle cluster source. The vibrationally and rotationally resolved electronic spectra obtained for these complexes help to determine the complexes' structures and bonding energetics. Observations from these studies have provided many new insights into the fundamental interactions in electrostatic bonding.
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页码：69 / 93
页数：25
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