Improving the Capacity of Polypropylene To Be Used in Antioxidant Active Films: Incorporation of Plasticizer and Natural Antioxidants

被引:33
作者
Castro Lopez, Maria del Mar [1 ]
Lopez de Dicastillo, Carol [1 ]
Lopez Vilarino, Jose Manuel [1 ]
Gonzalez Rodriguez, Maria Victoria [1 ]
机构
[1] Univ A Coruna, Grp Polimeros, CIT, Ferrol 15403, Spain
关键词
active packaging; antioxidant; PP; PPG-PEG-PPG; green tea; flavonoids; CONTROLLED-RELEASE; ALPHA-TOCOPHEROL; GREEN TEA; DENSITY POLYETHYLENE; LLDPE FILMS; GRAPE SEED; FOODS; QUERCETIN; MIGRATION; PHENOLICS;
D O I
10.1021/jf402670a
中图分类号
S [农业科学];
学科分类号
09 ;
摘要
Two types Of active antioxidant food packages With improved release properties, based on Polypropylene.(PP) as one of the most common polymers used in food packaging applications,. were developed. Incorporation of catechin and green tea as antioxidant provided PP with 6 times higher stabilization against thermal oxidation: Release of natural antioxidants (catechins, gallic acid, caffeine, and quercetin) into :various food simulants from that nonpolar matrix were improved by blending poly(propylene glycol)-block-poly(ethylene glycol)-block-poly(propylene glycol) (PPG-PEG-PPG) as plasticizer into the polymer formulation. Increasing release levels between 10- and 40 fold into simulant A and between 6 and 20 fold into simulant D1 resulted, from the incorporation of catechin and green tea as antioxidants and PPG-PEG-PPG as plasticizer into the film formulation. The efficiency : Of the antioxidants in the food simulants after the release process was also corroborated through :antioxidant activity tests. Therefore, the developed PPG-PEG-PPG-modified polypropylene resulted in a potential system to be, used in active packaging.
引用
收藏
页码:8462 / 8470
页数:10
相关论文
共 44 条
[1]   The antioxidant role of α-tocopherol in polymers II.: Melt stabilising effect in polypropylene [J].
Al-Malaika, S ;
Goodwin, C ;
Issenhuth, S ;
Burdick, D .
POLYMER DEGRADATION AND STABILITY, 1999, 64 (01) :145-156
[2]  
[Anonymous], 7281997 EN EUR COMM
[3]   Incorporating phenolic compounds opens a new perspective to use zein films as flexible bioactive packaging materials [J].
Arcan, Iskender ;
Yemenicioglu, Ahmet .
FOOD RESEARCH INTERNATIONAL, 2011, 44 (02) :550-556
[4]  
Avendano L, 1992, INICIACION PLASTICOS, P29
[5]   UPLC-Q-TOF-MS analysis of non-volatile migrants from new active packaging materials [J].
Aznar, M. ;
Rodriguez-Lafuente, A. ;
Alfaro, P. ;
Nerin, C. .
ANALYTICAL AND BIOANALYTICAL CHEMISTRY, 2012, 404 (6-7) :1945-1957
[6]   Direct determination of carnosic acid in a new active packaging based on natural extract of rosemary [J].
Bentayeb, K. ;
Rubio, C. ;
Batlle, R. ;
Nerin, C. .
ANALYTICAL AND BIOANALYTICAL CHEMISTRY, 2007, 389 (06) :1989-1996
[7]   Effect of PPG-PEG-PPG on the Tocopherol-Controlled Release from Films Intended for Food-Packaging Applications [J].
Castro Lopez, Maria del Mar ;
Dopico Garcia, Sonia ;
Ares Pernas, Ana ;
Lopez Vilarino, Jose Manuel ;
Gonzalez Rodriguez, Maria Victoria .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2012, 60 (33) :8163-8170
[8]   Release Kinetics of Tocopherol and Quercetin from Binary Antioxidant Controlled-Release Packaging Films [J].
Chen, Xi ;
Lee, Dong Sun ;
Zhu, Xuntao ;
Yam, Kit L. .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2012, 60 (13) :3492-3497
[9]   Role of Catechins in the Antioxidant Capacity of an Active Film Containing Green Tea, Green Coffee, and Grapefruit Extracts [J].
Colon, M. ;
Nerin, C. .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2012, 60 (39) :9842-9849
[10]   Antimicrobial properties of grape seed extracts and their effectiveness after incorporation into pea starch films [J].
Corrales, Margarita ;
Han, Jung H. ;
Tauscher, Bernhard .
INTERNATIONAL JOURNAL OF FOOD SCIENCE AND TECHNOLOGY, 2009, 44 (02) :425-433