Photo-initiated post-polymerization in micellar system of amphiphilic poly(ethylene oxide) macromonomers

被引：0
|
作者：
Maruyama, R [1 ]
Maniruzzaman, M [1 ]
Kawaguchi, S [1 ]
Ito, K [1 ]
机构：
[1] Toyohashi Univ Technol, Dept Mat Sci, Toyohashi, Aichi 4418580, Japan
来源：
MACROMOLECULAR SYMPOSIA | 2002年 / 179卷
关键词：
D O I：
10.1002/1521-3900(200203)179:1<133::AID-MASY133>3.0.CO;2-3
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Aqueous micellar polymerization of amphiphilic poly(ethylene oxide) macromonomers carrying p-vinylphenylheptyl end-group has been found to persist to proceed after turning-off of the UV-irradiation. Simulation of the kinetics revealed a high propagation rate constant coupled with a low termination constant, supporting a living-like polymerization at the initial stage. Micellar copolymerization with equimolar styrene also proceeded after UV-irradiation. Polymer molecular weights in MALLS-SEC were also found to evolve with time after irradiation.
引用
收藏
页码：133 / 140
页数：8
相关论文
共 50 条
  • [1] Amphiphilic poly(ethylene oxide) macromonomers, polymerization and copolymerization
    Ito, K
    Maniruzzaman, M
    Nishimura, H
    Hattori, T
    Tano, K
    Kawaguchi, S
    TAILORED POLYMERS & APPLICATIONS, 2000, : 15 - 23
  • [2] Micellar polymerization behavior of α,ω-divinylbenzyl poly (ethylene oxide) macromonomers
    Kawaguchi, S
    Shibata, Y
    Sudo, T
    Ito, K
    KOBUNSHI RONBUNSHU, 2001, 58 (06) : 311 - 317
  • [3] POLY(ETHYLENE OXIDE) MACROMONOMERS .7. MICELLAR POLYMERIZATION IN WATER
    ITO, K
    TANAKA, K
    TANAKA, H
    IMAI, G
    KAWAGUCHI, S
    ITSUNO, S
    MACROMOLECULES, 1991, 24 (09) : 2348 - 2354
  • [4] Photo-initiated polymerization of cyclohexene oxide by dirhenium decacarbonyl
    Abu-Abdoun, II
    POLYMER INTERNATIONAL, 1999, 48 (12) : 1197 - 1201
  • [5] POLY(ETHYLENE OXIDE) MACROMONOMERS .5. DODECYLOXY POLY(ETHYLENE GLYCOL) METHACRYLATE AS AN AMPHIPHILIC MACROMONOMER FOR DISPERSION POLYMERIZATION
    ITO, K
    YOKOYAMA, S
    ARAKAWA, F
    POLYMER BULLETIN, 1986, 16 (04) : 345 - 349
  • [6] Modification of graphene oxide via photo-initiated grafting polymerization
    Song, Kai
    Zhao, Xiaoying
    Xu, Yueming
    Liu, Hewen
    JOURNAL OF MATERIALS SCIENCE, 2013, 48 (17) : 5750 - 5755
  • [7] Modification of graphene oxide via photo-initiated grafting polymerization
    Kai Song
    Xiaoying Zhao
    Yueming Xu
    Hewen Liu
    Journal of Materials Science, 2013, 48 : 5750 - 5755
  • [8] Radical polymerization kinetics of poly(ethylene oxide) macromonomers
    Nomura, E
    Ito, K
    Kajiwara, A
    Kamachi, M
    MACROMOLECULES, 1997, 30 (10) : 2811 - 2817
  • [9] Photo-Initiated Lamination of Polyethylene (PE) and Poly(ethylene terephthalate) (PET)
    Bahners, Thomas
    Gutmann, Jochen S.
    JOURNAL OF ADHESION SCIENCE AND TECHNOLOGY, 2012, 26 (1-3) : 121 - 130
  • [10] POLY(ETHYLENE OXIDE) MACROMONOMERS .8. PREPARATION AND POLYMERIZATION OF OMEGA-HYDROXYPOLY(ETHYLENE OXIDE) MACROMONOMERS
    ITO, K
    HASHIMURA, K
    ITSUNO, S
    YAMADA, E
    MACROMOLECULES, 1991, 24 (14) : 3977 - 3981
12345