Stoichiometric Metal-Free Reduction of CO in Syn-Gas

被引：121

作者：

Dobrovetsky, Roman ^{[1
]}

Stephan, Douglas W. ^{[1
]}

机构：

[1] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2013年 / 135卷 / 13期

基金：

加拿大自然科学与工程研究理事会;

关键词：

FRUSTRATED LEWIS PAIRS; CARBON-MONOXIDE; HYDROGENATION CATALYSIS; ACTIVATION; INSERTION; (CF3)(3)BCO; DIHYDROGEN; EXISTENCE; CARBENES; AMMONIA;

D O I：

10.1021/ja401492s

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of a 2:1 mixture of B(C6F5)(3) and tBu(3)P with syn-gas results in the stoichiometric reduction of CO to give a formyl derivative which reacts further via an epoxy-borate intermediate to capture CO, affording a heterocylic alkoxyborate. Heating the reaction prompts reaction with H-2 to give a borane-oxy-borate derivative, the product of C-O bond cleavage.

引用

页码：4974 / 4977

页数：4

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