Redox-active cyclopentadienyl Ni complexes with quinoid N-heterocyclic carbene ligands for the electrocatalytic hydrogen release from chemical fuels

被引：65

作者：

Luca, Oana R. ^{[1
]}

Huang, Daria L. ^{[1
]}

Takase, Michael K. ^{[1
]}

Crabtree, Robert H. ^{[1
]}

机构：

[1] Yale Univ, Dept Chem, New Haven, CT 06520 USA

来源：

NEW JOURNAL OF CHEMISTRY | 2013年 / 37卷 / 11期

关键词：

DEHYDROGENATION; STORAGE;

D O I：

10.1039/c3nj00276d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We now report the electrocatalytic dehydrogenation of tetra-hydroquinaldine by an electron-rich CpNi N-heterocyclic carbene (NHC) with quinoid ligand motifs and explore the effects of quinone additives on CpNi compounds without quinoid NHC ligands. Our CpNi(NHC) catalyst exhibits dehydrogenative electrocatalytic activity and demonstrates that a molecular catalyst precursor can be viable in the electrode-driven (H+ + e(-)) release step of "virtual hydrogen storage''.

引用

页码：3402 / 3405

页数：4

共 18 条

[11] Popp B.V., 2007, ORGANOMETALLIC OXIDA
[12] Similarities between the reactions of dioxygen and alkenes with palladium(0): Relevance to the use of benzoquinone and molecular oxygen as stoichiometric oxidants in palladium-catalyzed oxidation reactions
Popp, Brian V.
Thorman, Joseph L.
Stahl, Shannon S.
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2006, 251 (1-2) : 2 - 7
[13] Preparation of a N-Heterocyclic Carbene Nickel(II) Complex Synthetic Experiments in Current Organic and Organometallic Chemistry
Ritleng, Vincent
Brenner, Eric
Chetcuti, Michael J.
[J]. JOURNAL OF CHEMICAL EDUCATION, 2008, 85 (12) : 1646 - 1648
[14] Half-sandwich NHC-nickel(II) complexes as pre-catalysts for the fast Suzuki coupling of aryl halides: a comparative study
Ritleng, Vincent
Oertel, Anna Magdalena
Chetcuti, Michael J.
[J]. DALTON TRANSACTIONS, 2010, 39 (35) : 8153 - 8160
[15] Quinone-annulated N-heterocyclic carbene-transition-metal complexes:: Observation of π-backbonding using FT-IR spectroscopy and cyclic voltammetry
Sanderson, Matthew D.
Kamplain, Justin W.
Bielawski, Christopher W.
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (51) : 16514 - 16515
[16] Electron Sharing and Anion-π Recognition in Molecular Triangular Prisms
Schneebeli, Severin T.
Frasconi, Marco
Liu, Zhichang
Wu, Yilei
Gardner, Daniel M.
Strutt, Nathan L.
Cheng, Chuyang
Carmieli, Raanan
Wasielewski, Michael R.
Stoddart, J. Fraser
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (49) : 13100 - 13104
[17] Soloveichik GL, 2008, US Patent Appl, Patent No. [2008/0248339, 20080248339]
[18] Homogeneous dehydrogenation of liquid organic hydrogen carriers catalyzed by an iridium PCP complex
Wang, Zhaohui
Belli, Jack
Jensen, Craig M.
[J]. FARADAY DISCUSSIONS, 2011, 151 : 297 - 305

← 1 2 →