Organic functionalization of metal catalysts: Enhanced activity towards electroreduction of carbon dioxide

被引：29

作者：

Wang, Jigang ^{[1
]}

Zhang, Fengqi ^{[1
]}

Kang, Xiongwu ^{[1
]}

Chen, Shaowei ^{[1
,2
]}

机构：

[1] South China Univ Technol, Guangzhou Higher Educ Mega Ctr, Sch Environm & Energy, Guangzhou Key Lab Surface Chem Energy Mat,New Ene, Guangzhou 510006, Guangdong, Peoples R China

[2] Univ Calif Santa Cruz, Dept Chem & Biochem, 1156 High St, Santa Cruz, CA 95064 USA

来源：

CURRENT OPINION IN ELECTROCHEMISTRY | 2019年 / 13卷

基金：

美国国家科学基金会;

关键词：

CO2; reduction; Transition metal; Surface functionalization; Geometrical effect; Interfacial charge transfer; SELECTIVE ELECTROCHEMICAL REDUCTION; ELECTROCATALYTIC ACTIVITY; SURFACE FUNCTIONALIZATION; OXYGEN REDUCTION; CO2; REDUCTION; NANOPARTICLES; BONDS;

D O I：

10.1016/j.coelec.2018.10.010

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Electrochemical reduction of carbon dioxide has been attracting extensive interest due to its fundamental significance both in environmental protection and in energy storage. In this review, recent progress in the manipulation of the catalytic activity and selectivity of various transition metals towards CO2 reduction reaction (CO2RR) is summarized within the context of deliberate surface functionalization by select organic ligands. This is primarily manifested in three effects, interfacial charge transfer, suppression of hydrogen evolution, and stabilization of key reaction intermediates. The review is concluded with a perspective of the challenges and promises in the structural engineering of metal catalysts for enhanced CO2RR performance.

引用

页码：40 / 46

页数：7

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