Non-destructive approach to multilayer objects: XRF analysis of gilt and enamelled metals of the medieval cross of Rosciolo

被引:2
作者
Campanella, Luigi [1 ]
Ferretti, Marco [2 ]
Polese, Claudia [1 ]
Roldan Garcia, Clodoaldo [3 ]
Sabatini, Irene [4 ]
机构
[1] Univ Rome Sapienza, Dip Chim, Piazzale Aldo Moro 5, I-00175 Rome, Italy
[2] CNR, Ist Tecnol Tecnol Applicate Beni Culturali, I-00016 Monterotondo, Italy
[3] Univ Valencia, Inst Ciencia Mat, I-46980 Espana, Spain
[4] Univ Florence, Dip Storia Arti & Spettacolo, I-50121 Florence, Italy
来源
YOUTH IN THE CONSERVATION OF CULTURAL HERITAGE, YOCOCU 2012 | 2013年 / 8卷
关键词
X-ray fluorescence; multilayered materials; fundamental parameter; medieval processional cross; gilt silver; enamels;
D O I
10.1016/j.proche.2013.03.035
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The penetration of X-rays is usually a limitation to the application of XRF analysis to multilayered materials, however it is possible, by software tools based on the fundamental parameters method, to overcome this problem and estimate thickness and composition of each layer. The cross of Rosciolo is a significant example of multilayer object: it is made of a wood core with attached gilt silver sheets and decorated with enamels. Measurements were carried out in situ and the PyMCA software was employed. The values of gilding thickness, Au/Hg ratios and Cu content in the silver sheets, and enamel's composition are discussed. (C) 2013 The Authors. Published by Elsevier B.V. Selection and peer-review under responsibility of the IA-CS (Italian Association of Conservation Scientists) and University of Antwerp
引用
收藏
页码:284 / 291
页数:8
相关论文
共 16 条
[1]  
Belluzzo P., 2011, OPD RESTAURO, V23, P82
[2]  
Berardo M., 1991, ANN SCUOLA NORM SU L, V21, P359
[3]   Metal location and thickness in a multilayered sheet by measuring Kα/Kβ, Lα/Lβ and Lα/Lγ X-ray ratios [J].
Cesareo, Roberto ;
Rizzutto, Marcia A. ;
Brunetti, Antonio ;
Rao, Donepudi V. .
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 2009, 267 (17) :2890-2896
[4]   Revealing the sfumato Technique of Leonardo da Vinci by X-Ray Fluorescence Spectroscopy [J].
de Viguerie, Laurence ;
Walter, Philippe ;
Laval, Eric ;
Mottin, Bruno ;
Sole, V. Armando .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (35) :6125-6128
[5]  
Fabrizi A., 1929, CAPITOLIUM, VVIII, P393
[6]  
Gratuze B, 2005, TRADE DISCOVERY STIE
[7]  
Gratuze B., 1992, Revue d'Archeometrie, V16, P97, DOI DOI 10.3406/ARSCI.1992.895
[8]  
Henderson J., 1999, PATTERNS PROCESS, P228
[9]  
Lipinsky A., 1967, NAPOLI NOBILISSIMA, VVI, P123
[10]  
Mattiocco E., 2004, ORAFI ARGENTIERI ABR, P123