Substitute group-tuned Schiff-base manganese(III)-based cyanide-bridged bimetallic complexes: synthesis, crystal structures and magnetic properties

被引：4

作者：

Shi, Jingwen ^{[1
]}

Zhou, Yin ^{[1
]}

Xue, Chongchong ^{[1
]}

Liu, Qingyun ^{[2
]}

Zhang, Daopeng ^{[1
]}

机构：

[1] Shandong Univ Technol, Coll Chem & Chem Engn, Zibo 255049, Peoples R China

[2] Shandong Univ Sci & Technol, Coll Chem & Environm Engn, Qingdao 266510, Peoples R China

来源：

JOURNAL OF CHEMICAL RESEARCH | 2018年 / 01期

关键词：

cyanide-bridged; heterometallic Pt-Mn; Schiff base; crystal structure; magnetic properties; SPIN-CROSSOVER BEHAVIOR; TRANSITION; POLYNUCLEAR; 1D;

D O I：

10.3184/174751918X15161933697826

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The trinuclear cyanide-bridged heterometallic Pd(II)-Mn(III) complexes {[Mn(L-1)(H2O)](2) [Pd(CN)(4)]} and {[Mn(L-2)(H2O)](2)[Pd(CN)(4)]}center dot 2H(2)O (L-1 = N,N'-1,2-propylene-bis(3-methoxysalicylideneiminate; L-2 = N,N'-1,2-propylene-bis(3-ethoxysalicylideneiminate) were obtained and structurally and magnetically characterised. X-ray diffraction revealed their cyanide-bridged trinuclear core nature with a conformational difference. The magnetic susceptibilities of the two complexes revealed overall weak antiferromagnetic interactions between the adjacent Mn(III) ions.

引用

页码：28 / 32

页数：5

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