Coupling of aromatic aldehydes with aryl halides in the presence of nickel catalysts with diazabutadiene ligands

被引：15

作者：

Asachenko, A. F. ^{[1
]}

Valaeva, V. N. ^{[1
]}

Kudakina, V. A. ^{[1
]}

Uborsky, D. V. ^{[1
]}

Izmer, V. V. ^{[1
]}

Kononovich, D. S. ^{[1
]}

Voskoboynikov, A. Z. ^{[1
]}

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, Bldg 3,1 Leninskie Gory, Moscow 119991, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2016年 / 65卷 / 02期

关键词：

cross-coupling; benzaldehydes; aryl halides; benzhydrols; benzophenones; nickel catalysts; ARYLBORONIC ACIDS; BIARYL KETONES; ARYLATION; CHEMISTRY;

D O I：

10.1007/s11172-016-1321-3

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Nickel catalysts with diazabutadiene ligands promote cross-coupling of benzaldehydes with aryl halides in the presence of zinc as reducing agent, which leads to the corresponding benzhydrols and benzophenones. The benzophenone percentage considerably increases when lithium chloride additive is used.

引用

页码：456 / 463

页数：8

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