The analyses of the start-up process of a planar, anode-supported solid oxide fuel cell using three different start-up procedures

被引:17
作者
Chen, Ming-Hong [2 ]
Jiang, Tsung Leo [1 ]
机构
[1] Natl Cheng Kung Univ, Dept Aeronaut & Astronaut, Tainan 70101, Taiwan
[2] Atom Energy Council, Inst Nucl Energy Res, Environm & Energy Technol Ctr, Tao Yuan 32546, Taiwan
关键词
Solid oxide fuel cell; Transient; Simulation; Start-up; THERMAL-STRESS ANALYSIS; ELECTROCHEMICAL MODEL; HEAT/MASS TRANSFER; FINITE-VOLUME; STEADY-STATE; SOFC; PERFORMANCE; SIMULATION; TRANSPORT; DESIGN;
D O I
10.1016/j.jpowsour.2012.08.018
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Three start-up procedures for an anode-supported planar SOFC are proposed and investigated numerically in the present study. The first is to introduce the inlet fuel at the operation temperature after the heat-up process is completed. The second is to incorporate the anode-recycling mechanism into the start-up process. The third is to fix the difference between the inlet-fuel temperature and the cell minimum temperature. The numerical results obtained from the present study show that the effective maximum absolute temperature-gradient is exhibited in the early stage of the start-up process. For the present investigated SOFC configuration, the required start-up time for the case using methane is 3.2-fold longer than that using hydrogen. The effective maximum absolute temperature-gradient for the case using hydrogen is 2.2-fold larger than that utilizing methane. The endothermic internal reforming reaction of methane has a positive effect on the accommodation of the temperature uniformity during the start-up process. The anode-recycling mechanism significantly reduces the start-up time For the fixed-temperature-difference start-up procedure, a properly selected temperature difference may lead to a smaller effective maximum absolute temperature-gradient in the early stage and a shorter start-up time by accelerating the start-up pace in the later stage. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:331 / 341
页数:11
相关论文
共 36 条
[1]   3-DIMENSIONAL AND TIME-DEPENDENT SIMULATION OF A PLANAR SOLID OXIDE FUEL-CELL STACK [J].
ACHENBACH, E .
JOURNAL OF POWER SOURCES, 1994, 49 (1-3) :333-348
[2]   Anode-supported intermediate temperature direct internal reforming solid oxide fuel cell. I: model-based steady-state performance [J].
Aguiar, P ;
Adjiman, CS ;
Brandon, NP .
JOURNAL OF POWER SOURCES, 2004, 138 (1-2) :120-136
[3]   Anode-supported intermediate-temperature direct internal reforming solid oxide fuel cell - II. Model-based dynamic performance and control [J].
Aguiar, P ;
Adjiman, CS ;
Brandon, NP .
JOURNAL OF POWER SOURCES, 2005, 147 (1-2) :136-147
[4]  
[Anonymous], 2006, FLUENT 6 3 US GUID
[5]   Numerical analysis of start-up operation of a tubular solid oxide fuel cell [J].
Barzi, Y. Mollayi ;
Ghassemi, M. ;
Hamedi, M. H. .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2009, 34 (04) :2015-2025
[6]   A complete polarization model of a solid oxide fuel cell and its sensitivity to the change of cell component thickness [J].
Chan, SH ;
Khor, KA ;
Xia, ZT .
JOURNAL OF POWER SOURCES, 2001, 93 (1-2) :130-140
[7]   Internal reforming of hydrocarbon fuels in tubular solid oxide fuel cells [J].
Cheekatamarla, P. K. ;
Finnerty, Caine M. ;
Cai, Jun .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2008, 33 (07) :1853-1858
[8]   The analyses of the heat-up process of a planar, anode-supported solid oxide fuel cell using the dual-channel heating strategy [J].
Chen, Ming-Hong ;
Jiang, Tsung Leo .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2011, 36 (11) :6882-6893
[9]   Thermo-electrochemical and thermal stress analysis for an anode-supported SOFC cell [J].
Chiang, Lieh-Kwang ;
Liu, Hui-Chung ;
Shiu, Yao-Hua ;
Lee, Chien-Hsiung ;
Lee, Ryey-Yi .
RENEWABLE ENERGY, 2008, 33 (12) :2580-2588
[10]   A methodology for optimizing the start-up scenario of solid oxide fuel cell utilizing transient analyses [J].
Chyou, Yau-Pin ;
Chen, Jong-Sheng ;
Chung, Tsang-Dong .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2008, 155 (07) :B650-B659