Oxidation of alcohols with catalytic amounts of IBX

被引：74

作者：

Schulze, A ^{[1
]}

Giannis, A ^{[1
]}

机构：

[1] Univ Leipzig, Inst Organ Chem, D-04103 Leipzig, Germany

来源：

SYNTHESIS-STUTTGART | 2006年 / 02期

关键词：

alcohols; aldehydes; catalytic oxidation; carboxylic acids; ketones;

D O I：

10.1055/s-2005-924764

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Herein we present a catalytic IBX-based method for the oxidation of alcohols. Using this system a variety of benzylic alcohols were transformed to aldehydes in good yields whereas secondary alcohols were easily converted to ketones. Primary aliphatic alcohols were oxidised to the corresponding carboxylic acids. 2-Io-dobenzoic acid can also be used instead of IBX.

引用

页码：257 / 260

页数：4

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