CuBr/proline-catalyzed cross-coupling of unactivated benzene with aryl halides

被引：7

作者：

Liu, Wei ^{[1
]}

Hou, Fanyi ^{[1
]}

机构：

[1] Henan Univ Technol, Coll Food Sci & Technol, Zhengzhou 450001, Henan, Peoples R China

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 2015年 / 29卷 / 06期

基金：

中国国家自然科学基金;

关键词：

Cu catalysis; CH activation; direct CH arylation; unactivated arenes; aryl halides; C-H ARYLATION; BOND FORMATION; ARENES; PALLADIUM; NAPHTHALENE; ACTIVATION; PRODUCTS; ACID;

D O I：

10.1002/aoc.3300

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Direct CH arylation of unactivated benzene with aryl halides was achieved using a readily available copper catalyst. The reaction was carried out at 80 degrees C, using CuBr as catalyst, proline as ligand and t-BuOK as base. This radical cross-coupling reaction between unactivated benzene and aryl iodides proceeds via homolytic aromatic substitution and offers an efficient method for the synthesis of various biaryls in good to excellent yields. Copyright (c) 2015 John Wiley & Sons, Ltd.

引用

页码：368 / 371

页数：4

共 50 条

[21] Hiyama Cross-Coupling Reaction of Aryl Vinylsilanes and Aryl Halides
Ma Wei-Yuan
Dai Huifang
Kang Shaolin
Zhang Tianlin
Shu Xing-Zhong
CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2023, 43 (10) : 3614 - 3622
[22] Palladium-Catalyzed C-P Cross-Coupling between (Het)aryl Halides and Secondary Phosphine Oxides
Zakirova, Gladis G.
Mladentsev, Dmitrii Yu.
Borisova, Nataliya E.
SYNTHESIS-STUTTGART, 2019, 51 (11): : 2379 - 2386
[23] Oxidative cycloaddition and cross-coupling processes on unactivated benzene derivatives
Jacquemot, Guillaume
Menard, Marc-Andre
L'Homme, Chloe
Canesi, Sylvain
CHEMICAL SCIENCE, 2013, 4 (03) : 1287 - 1292
[24] Cobalt-Catalyzed Reductive Cross-Coupling Between Benzyl Chlorides and Aryl Halides
Pal, Suman
Chowdhury, Sushobhan
Rozwadowski, Elodie
Auffrant, Audrey
Gosmini, Corinne
ADVANCED SYNTHESIS & CATALYSIS, 2016, 358 (15) : 2431 - 2435
[25] Palladium-Catalyzed Cross-Coupling of 2,3-Naphthoxadisilole with Aryl Halides
Ding, Han
Chen, Yali
Cao, Weiguo
Wu, Kaicheng
Chen, Jie
Lee, Albert W. M.
SYNTHETIC COMMUNICATIONS, 2010, 40 (07) : 984 - 991
[26] Indium-Catalyzed C-S Cross-Coupling of Aryl Halides with Thiols
Reddy, V. Prakash
Swapna, K.
Kumar, A. Vijay
Rao, K. Rama
JOURNAL OF ORGANIC CHEMISTRY, 2009, 74 (08) : 3189 - 3191
[27] CuI/DABCO-catalyzed cross-coupling reactions of aryl halides with arylboronic acids
Li, Jin-Heng
Wang, De-Ping
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2006, 2006 (09) : 2063 - 2066
[28] An efficient catalyst system for palladium(0)-catalyzed cross-coupling of aryltrialkoxysilanes with aryl halides
Murata, M
Yoshida, S
Nirei, S
Watanabe, S
Masuda, Y
SYNLETT, 2006, (01) : 118 - 120
[29] Cobalt(II)-catalyzed preparation of alkylindium reagents and applications in cross-coupling with aryl halides
Wang, Peng
Song, Xuan-Di
Chen, Bing-Zhi
Rao, Weidong
Shen, Zhi-Liang
CATALYSIS COMMUNICATIONS, 2019, 132
[30] Synthesis of unsymmetrical biaryls by electroreductive cobalt-catalyzed cross-coupling of aryl halides
Gomes, P
Fillon, H
Gosmini, C
Labbé, E
Périchon, J
TETRAHEDRON, 2002, 58 (42) : 8417 - 8424

← 1 2 3 4 5 →