Catalytic combustion of toluene over Fe-Mn mixed oxides supported on cordierite

被引:50
|
作者
Ma, W. J. [1 ,2 ]
Huang, Q. [1 ,2 ]
Xu, Y. [1 ,2 ]
Chen, Y. W. [1 ,2 ]
Zhu, S. M. [1 ,3 ]
Shen, S. B. [1 ,2 ]
机构
[1] State Key Lab Mat Oriented Chem Engn, Nanjing 210009, Jiangsu, Peoples R China
[2] Nanjing Univ Technol, Coll Life Sci & Pharmaceut Engn, Nanjing 210009, Jiangsu, Peoples R China
[3] Nanjing Univ Technol, Coll Mat Sci & Engn, Nanjing 210009, Jiangsu, Peoples R China
关键词
Cordierite; Fe-Mn mixed oxides; Catalytic combustion; Catalysts; VOCS COMBUSTION; METAL CATALYSTS; OXIDATION; PALLADIUM; REMOVAL; CO;
D O I
10.1016/j.ceramint.2012.06.022
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The catalytic combustion of toluene over Fe-Mn mixed oxides supported on cordierite was investigated. The catalysts were synthesized by the impregnation method and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and BET specific surface area measurement. The effects of the mole ratio of Fe to Mn, the loading of Fe-Mn mixed oxides on the catalyst support and the calcination temperature were all investigated. The results indicate that Fe-Mn/cordierite catalysts with a 4 mol ratio of Fe to Mn, used with 10 wt% loading, and calcined at 500 degrees C showed the highest catalytic activities as measured by the oxidation of toluene. Compared to unsupported powder catalysts of Fe Mn mixed oxides, the Fe-Mn/cordierite catalyst showed higher activity for the catalytic combustion of toluene with less active component. (C) 2012 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
引用
收藏
页码:277 / 281
页数:5
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