Synthesis, Structural, and Electronic Properties of K4Puv102(CO3)3(co: An Environmentally Relevant Plutonium Carbonate Complex

被引：10

作者：

Pidchenko, Ivan ^{[1
,3
]}

Maerz, Juliane ^{[1
]}

Hunault, Myrtille O. J. Y. ^{[2
]}

Bauters, Stephen ^{[1
,3
]}

Butorin, Sergei M. ^{[4
]}

Kvashnina, Kristina O. ^{[1
,3
]}

机构：

[1] Helmholtz Zcotrunt Dresden Rossendolf, Inst Resource Ecol, D-01314 Dresden, Germany

[2] Synchrotron SOLEIL, LOrme Merisiers, F-91192 Gif Sur Yvette, France

[3] ESRF European Synchrotron, Rossendolf Beamline, CS40220, F-38043 Grenoble 9, France

[4] Uppsala Univ, Dept Phys & Astron, Mol & Condensed Matter Phys, S-75236 Uppsala, Sweden

来源：

INORGANIC CHEMISTRY | 2020年 / 59卷 / 17期

基金：

瑞典研究理事会; 欧洲研究理事会;

关键词：

CRYSTAL-FIELD; SPECTROSCOPY; TRANSPORT; PROBE;

D O I：

10.1021/acs.inorgchem.0c01335

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The chevmic properties;al of ac tint a ematerials are oftenen pre n fine 1d described based o nth e datavailablea;for isostructural species. This isfhoasefor potassium,iutonyi(puvi) carbunate'I(4ru o2tco 3 a c relevant'for technologyandthe environment, of walc.tne crystallographic and thermodynamic propertiesof whiCharestilllaco.og.We report hrethesynt and characterization of PU achievedb single x-ray diffiacido3analysisand high-energy-resolution fiiorescence-dc:edXraydbsorptiunnear-edge structure at the M4 edgecoup--dwithelectruntcstructure calculations"The of with isostructural (U) andnePtuniun (Np) compounds.,ctinyIAn axial lengths,hs r0 lv-012+arecorrelatedne'weensciid'4nvto2(CO3)3(cr)' and aqueous, [Af3 2(c03)3] (ac) spec for theuvNv_ptseries.Thespectroscopic data are to Puvo2(c)totackle the trendin atom.

引用

页码：11889 / 11893

页数：5

共 33 条

[1]

ALENCHIKOVA IF, 1958, ZH NEORG KHIM+, V3, P951

[2] AN X-RAY CRYSTALLOGRAPHIC, RAMAN, AND INFRARED SPECTRAL STUDY OF CRYSTALLINE POTASSIUM URANYL CARBONATE, K4UO2(CO3)3 [J].

ANDERSON, A ;

CHIEH, C ;

IRISH, DE ;

TONG, JPK .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1980, 58 (16) :1651-1658

[3] LOCALIZED MAGNETIC STATES IN METALS [J].

ANDERSON, PW .

PHYSICAL REVIEW, 1961, 124 (01) :41-&

[4] An Updated Version of the Computational Package SIMPRE that Uses the Standard Conventions for Stevens Crystal Field Parameters [J].

Baldovi, Jose J. ;

Clemente-Juan, Juan M. ;

Coronado, Eugenio ;

Gaita-Arino, Alejandro ;

Palii, Andrew .

JOURNAL OF COMPUTATIONAL CHEMISTRY, 2014, 35 (26) :1930-1934

[5] Probing Chemical Bonding in Uranium Dioxide by Means of High- Resolution X-ray Absorption Spectroscopy [J].

Butorin, Sergei M. ;

Modin, Anders ;

Vegelius, Johan R. ;

Kvashnina, Kristina O. ;

Shuh, David K. .

JOURNAL OF PHYSICAL CHEMISTRY C, 2016, 120 (51) :29397-29404

[6] High-resolution X-ray absorption spectroscopy as a probe of crystal-field and covalency effects in actinide compounds [J].

Butorin, Sergei M. ;

Kvashnina, Kristina O. ;

Vegelius, Johan R. ;

Meyer, Daniel ;

Shuh, David K. .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2016, 113 (29) :8093-8097

[7] Crystal-Field and Covalency Effects in Uranates: An X-ray Spectroscopic Study [J].

Butorin, Sergei M. ;

Kvashnina, Kristina O. ;

Smith, Anna L. ;

Popa, Karin ;

Martin, Philippe M. .

CHEMISTRY-A EUROPEAN JOURNAL, 2016, 22 (28) :9693-9698

[8] Resonant X-ray fluorescence spectroscopy of correlated systems: A probe of charge-transfer excitations [J].

Butorin, SM ;

Mancini, DC ;

Guo, JH ;

Wassdahl, N ;

Nordgren, J ;

Nakazawa, M ;

Tanaka, S ;

Uozumi, T ;

Kotani, A ;

Ma, Y ;

Myano, KE ;

Karlin, BA ;

Shuh, DK .

PHYSICAL REVIEW LETTERS, 1996, 77 (03) :574-577

[9] Crystal structure of complexes of Np(VI) and Pu(VI) perchlorates with triphenylphosphine oxide, [NpO2(OP(C6H5) 3)4](ClO4)2 and [PuO 2(OP(C6H5)3)4](ClO 4)2 [J].

Charushnikova I.A. ;

Krot N.N. ;

Starikova Z.A. ;

Polyakova I.N. .

Radiochemistry, 2007, 49 (5) :464-469

[10]

Clark D.L., 2000, LOS ALAMOS SCI, V2, P364

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