Self-assembly of a cadmium(II) diamondoid net with 2-fold interpenetrating microporous structure

被引：1
|
作者：
Wen, Gui-Lin [1 ]
Han, Min-Le [2 ]
Wang, Feng-Wu [1 ]
Liu, Dao-Fu [1 ]
Zhao, Xing [1 ]
机构：
[1] Huainan Normal Univ, Dept Chem & Chem Engn, Anhui Key Lab Low Temp Cofired Mat, Huainan 232001, Peoples R China
[2] Luoyang Normal Univ, Coll Chem & Chem Engn, Luoyang 471022, Peoples R China
来源：
CRYSTAL RESEARCH AND TECHNOLOGY | 2013年 / 48卷 / 05期
关键词：
cadmium coordination polymer; 5-methoxyisophthalic acid; microporous structure; 2-fold interpenetration; R-ISOPHTHALATE R; COORDINATION POLYMERS; CU-II; CONSTRUCTION; FRAMEWORKS; COMPLEXES; SQUARE; LIGAND; -CH3;
D O I：
10.1002/crat.201300065
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
Assembly of 5-methoxyisophthalic acid (H2moip) with cadmium(II) ions in the presence of neutral ancillary 1,3-bis(4-pyridyl)propane (bpp) yields a new coordination polymer, [Cd(moip)(bpp)(H2O)]n center dot nH(2)O (1). X-ray single-crystal diffraction determination reveals that complex 1 crystallizes in the space group C2/c of monoclinic crystal system: a = 14.545(2), b = 18.749(3), c = 17.359(3) angstrom, = 105.480(2)o. Complex 1 is a 4-connected 3D diamondoid topological framework with a 2-fold interpenetration. Interestingly, the dense adamantine cages with inherent microporous structure are filled with free water molecules to further stabilize the coordination network.
引用
收藏
页码：328 / 333
页数：6
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