CuS/RGO hybrid photocatalyst for full solar spectrum photoreduction from UV/Vis to near-infrared light

被引:67
作者
Wu, Jie [1 ,2 ]
Liu, Baibai [3 ]
Ren, Zhenxing [4 ]
Ni, Mengying [3 ]
Li, Can [3 ]
Gong, Yinyan [3 ]
Qin, Wei [5 ]
Huang, Yongli [1 ,2 ]
Sun, Chang Q. [6 ]
Liu, Xinjuan [3 ]
机构
[1] Xiangtan Univ, Key Lab Low Dimens Mat & Applicat Technol MOE, Xiangtan 411105, Hunan, Peoples R China
[2] Xiangtan Univ, Sch Mat Sci & Engn, Xiangtan 411105, Hunan, Peoples R China
[3] China Jiliang Univ, Coll Mat Sci & Engn, Inst Coordinat Bond Metrol & Engn, Hangzhou 310018, Zhejiang, Peoples R China
[4] Shanxi Univ, Inst Appl Chem, Taiyuan 030006, Shanxi, Peoples R China
[5] Sun Yat Sen Univ, Nanotechnol Res Ctr, Sch Mat Sci & Engn, State Key Lab Optoelect Mat & Technol, Guangzhou 510275, Guangdong, Peoples R China
[6] Nanyang Technol Univ, Sch Elect & Elect Engn, Singapore 639798, Singapore
基金
中国国家自然科学基金;
关键词
Full solar light spectrum active; CuS; RGO; Co-catalyst; Cr(VI); GRAPHENE OXIDE COMPOSITES; MICROWAVE-ASSISTED SYNTHESIS; ONE-POT; ORGANIC POLLUTANTS; REDUCTION; CR(VI); UV; NANOSHEETS; NANOCOMPOSITES; CUS;
D O I
10.1016/j.jcis.2017.09.042
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
To make full use of the solar energy, it remains a great challenge for semiconductor photocatalysts to harvest the full solar light spectrum from ultraviolet (UV) to visible even the near infrared (NIR) wavelength. Here we show firstly the CuS/RGO (reduced graphene oxide) hybrid photocatalyst synthesized via a microwave assisted method with full solar light (UV-Vis-NIR) active for efficient Cr(VI) reduction. The CuS/RGO displays high absorption and catalytic activity in the UV, visible and even the NIR light regions. As co-catalyst, RGO can separate and inhibit the recombination of charge carriers, consequently improving the catalytic activity. Only 1 wt% RGO emersions can reduce 90% of Cr(VI) under the radiation of light over the full spectrum. Findings may provide a new strategy and substance to expand the utilization range of solar light from UV to visible even the NIR energy. (C) 2017 Published by Elsevier Inc.
引用
收藏
页码:80 / 85
页数:6
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