Nitrogen-Rich Energetic Monoanionic Salts of 3,4-Bis(1H-5-tetrazolyl)furoxan

被引：60

作者：

Huang, Haifeng ^{[1
]}

Zhou, Zhiming ^{[1
,2
]}

Liang, Lixuan ^{[1
]}

Song, Jinhong ^{[1
]}

Wang, Kai ^{[1
]}

Cao, Dan ^{[1
]}

Sun, Wenwen ^{[1
]}

Bian, Chengming ^{[1
]}

Xue, Min ^{[1
]}

机构：

[1] Beijing Inst Technol, Sch Chem Engn & Environm, Beijing 100081, Peoples R China

[2] Beijing Inst Technol, State Key Lab Explos Sci & Technol, Beijing 100081, Peoples R China

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2012年 / 7卷 / 04期

关键词：

density functional calculations; detonation performance; energetic salts; heterocycles; tetrazoles; 5-SUBSTITUTED; 1H-TETRAZOLES; CATALYZED SYNTHESIS; FAMILY; NITRILES; PRECURSORS; HEATS; MONO;

D O I：

10.1002/asia.201100702

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

3,4-Bis(1H-5-tetrazolyl)furoxan (H2BTF, 2) and its monoanionic salts that contain nitrogen-rich cations were readily synthesized and fully characterized by multinuclear NMR (1H, 13C) and IR spectroscopy, differential scanning calorimetry (DSC), and elemental analyses. Hydrazinium (3) and 4-amino-1,2,4-triazolium (7) salts crystallized in the monoclinic space group P2(1)/n and have calculated densities of 1.820 and 1.764 g?cm-3, respectively. The densities of the energetic salts range between 1.63 and 1.79 g?cm-3, as measured by a gas pycnometer. Detonation pressures and detonation velocities were calculated to be 23.132.5 GPa and 77408790 m?s-1, respectively.

引用

页码：707 / 714

页数：8

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