X-ray single-crystal structure of a novel di-μ-chloro-bis[chloro(2,9-dimethyl-1,10-phenanthroline)nickel(II)] complex: synthesis, and spectral and thermal studies

被引：11

作者：

Warad, Ismail ^{[1
]}

Hammouti, Belkheir ^{[2
]}

Ben Hadda, Taibi ^{[3
]}

Boshaala, Ahmed ^{[4
]}

Haddad, Salim F. ^{[5
]}

机构：

[1] King Saud Univ, Coll Sci, Dept Chem, Riyadh 11451, Saudi Arabia

[2] Univ Mohammed Ier, Fac Sci, LCAE URAC18, Oujda 60000, Morocco

[3] Univ Mohammed Ier, FSO, Lab Chim Mat, Oujda 60000, Morocco

[4] Benghazi Univ, Fac Sci, Dept Chem, Benghazi, Libya

[5] Univ Jordan, Dept Chem, Amman 11942, Jordan

来源：

RESEARCH ON CHEMICAL INTERMEDIATES | 2013年 / 39卷 / 09期

关键词：

Nickel(II) dimer complex; Single-crystal structure; 2,9-Dimethyl-1,10-phenanthroline; METAL-COMPLEXES; DNA-BINDING; LUMINESCENT; NI; CO; 1,10-PHENANTHROLINE-5,6-DIONE; CU;

D O I：

10.1007/s11164-012-0917-y

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A binuclear nickel(II) chloride complex with dimethyl-1,10-phenanthroline, di-mu-chloro-bis[chloro(2,9-dimethyl-1,10-phenanthroline)nickel(II)] dimer, has been prepared and its molecular structure determined by X-ray diffraction. The crystal is triclinic, space group P-1, with the Ni(II) in [NiCl2(C14H12N2)](2) coordinated to two N of the phen ligand and three Cl-, one terminal and two bridging. A center of inversion lies midway between two Ni(II). Overall Ni(II) coordination is distorted triangular bipyramidal. The dimer complex was also characterized by elemental analysis, FAB-MS, IR and UV-visible spectroscopy, and thermogravimetric analysis.

引用

页码：4011 / 4020

页数：10

共 40 条

[1]

[Anonymous], 2015, Acta Crystallogr., V71, P3

[2] Dipyridophenazine complexes of cobalt(III) and nickel(II): DNA-Binding and photocleavage studies [J].