Effect of ionic liquids on the electrical and magnetic performance of polyaniline-nickel ferrite nanocomposite

被引:32
作者
Baykal, A. [1 ]
Gunay, M. [1 ]
Toprak, M. S. [2 ,3 ]
Sozeri, H. [4 ]
机构
[1] Fatih Univ, Dept Chem, Istanbul, Turkey
[2] KTH Royal Inst Technol, Funct Mat Div, SE-16440 Stockholm, Sweden
[3] Yildirim Beyazit Univ, Dept Mat Sci & Engn, Ankara, Turkey
[4] Natl Metrol Inst, TUBITAK UME, TR-41470 Gebze, Turkey
关键词
Composites; Magnetic materials; Nanostructures; Chemical synthesis; Electrical properties; Magnetic properties; COMBUSTION SYNTHESIS; NANOPARTICLES; CONDUCTIVITY; ROUTE;
D O I
10.1016/j.materresbull.2012.10.039
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Polyaniline-NiFe2O4 nanofiber composites were successfully synthesized at the interface of water and ionic liquid via in situ polymerization using cetyl trimethylammonium bromide (CAB) as surfactant. Both TG analysis and FT-IR measurements proved the presence of organic layer on the surface of NiFe2O4 nanoparticles. The influence of 1-butyl-3-methyl-imidazolium bromide [BMIM]Br as ionic liquid on the structure, conductivity and magnetic property of polyaniline-NiFe2O4-CFAB nanocomposite were studied in detail. The results show that imidazolium-based ionic liquids BMIMBr acts as an anchor agent for the formation of morphology in polyaniline-NiFe2O4-CTAB nanocomposite. Introduction of ionic liquids obviously improves the conductivity but weakens the magnetization of polyaniline-NiFe2O4 nanocomposite. (c) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:378 / 382
页数:5
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