Crystallite size and phase transition demeanor of ceramic steel

被引：8
作者：
Gusain, Deepak [1 ]
Srivastava, Varsha [1 ]
Singh, Vinay K. [2 ]
Sharma, Yogesh Chandra [1 ]
机构：
[1] Banaras Hindu Univ, Indian Inst Technol, Dept Chem, Varanasi 221005, Uttar Pradesh, India
[2] Banaras Hindu Univ, Indian Inst Technol, Dept Ceram Engn, Varanasi 221005, Uttar Pradesh, India
来源：
MATERIALS CHEMISTRY AND PHYSICS | 2014年 / 145卷 / 03期
关键词：
Ceramics; Chemical synthesis; Phase transitions; Surfaces; SOL-GEL; ZIRCONIA; STABILIZATION; TEMPERATURE;
D O I：
10.1016/j.matchemphys.2014.02.015
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Zirconia is an important oxide of zirconium used in variety of field ranging from dentistry, fuel cells, and thermal barrier coatings. Phase transition of zirconia is an important phenomenon controlling its fracture strength, low temperature degradability and ion conductivity. In the present study, effect of molar concentration of precursor and calcination temperature on phase transition and crystallite size of zirconia was investigated. All the samples were characterized by X-ray diffractometry (XRD), Differential Thermal Analysis/Thermogravimetric Analysis (DTA/TGA), Transmission electron microscopy (TEM), Scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR). In sample having lowest precursor concentration crystallite size of monoclinic zirconia was found to be lower than that of tetragonal zirconia, simultaneously with the higher proportion of tetragonal zirconia (67.62%) as compared to all other samples (42.75%-58.04%). In all cases, monoclinic to tetragonal phase transition occurs with raise of temperature but in the sample with lowest precursor concentration, tetragonal to monoclinic phase transition occurred on raising the temperature. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码：320 / 326
页数：7
相关论文
共 23 条
[1]   The Tetragonal-Monoclinic Transformation in Zirconia: Lessons Learned and Future Trends [J].
Chevalier, Jerome ;
Gremillard, Laurent ;
Virkar, Anil V. ;
Clarke, David R. .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2009, 92 (09) :1901-1920
[2]   Synthesis of thermally stable, high surface area, nanocrystalline mesoporous tetragonal zirconium dioxide (ZrO2): Effects of different process parameters [J].
Deshmane, Vishwanath G. ;
Adewuyi, Yusuf G. .
MICROPOROUS AND MESOPOROUS MATERIALS, 2012, 148 (01) :88-100
[3]   Effect of calcination temperature on structural, vibrational, optical, and rheological properties of zirconia nanoparticles [J].
Goharshadi, Elaheh K. ;
Hadadian, Mahboobeh .
CERAMICS INTERNATIONAL, 2012, 38 (03) :1771-1777
[4]   A nearly pure monoclinic nanocrystalline zirconia [J].
Guo, GY ;
Chen, YL .
JOURNAL OF SOLID STATE CHEMISTRY, 2005, 178 (05) :1675-1682
[5]   Synthesis and characterization of nanocrystalline zirconia powder by simple sol-gel method with glucose and fructose as organic additives [J].
Heshmatpour, Felora ;
Aghakhanpour, Reza Babadi .
POWDER TECHNOLOGY, 2011, 205 (1-3) :193-200
[6]   Nanosize stabilization of cubic and tetragonal phases in reactive plasma synthesized zirconia powders [J].
Jayakumar, S. ;
Ananthapadmanabhan, P. V. ;
Thiyagarajan, T. K. ;
Perumal, K. ;
Mishra, S. C. ;
Suresh, G. ;
Su, L. T. ;
Tok, A. I. Y. .
MATERIALS CHEMISTRY AND PHYSICS, 2013, 140 (01) :176-182
[7]   High refractive index and good mechanical property UV-cured hybrid films containing zirconia nanoparticles [J].
Luo, Kaiqing ;
Zhou, Shuxue ;
Wu, Limin .
THIN SOLID FILMS, 2009, 517 (21) :5974-5980
[8]   An overview of zirconia ceramics: Basic properties and clinical applications [J].
Manicone, Paolo Francesco ;
Iommetti, Pierfrancesco Rossi ;
Raffaelli, Luca .
JOURNAL OF DENTISTRY, 2007, 35 (11) :819-826
[9]   Synthesis and characterization of silica nanospheres using nonsurfactant template [J].
Misran, H. ;
Yarmo, M. A. ;
Ramesh, S. .
CERAMICS INTERNATIONAL, 2013, 39 (02) :931-940
[10]   CHEMISTRY OF ZIRCONIA AND ITS USE IN CHROMATOGRAPHY [J].
NAWROCKI, J ;
RIGNEY, MP ;
MCCORMICK, A ;
CARR, PW .
JOURNAL OF CHROMATOGRAPHY A, 1993, 657 (02) :229-282
123