Vibrational enhancement of electron emission in CO (a3Π) quenching at a clean metal surface

被引：8

作者：

Graetz, Fabian ^{[1
,2
,3
]}

Engelhart, Daniel P. ^{[1
,2
]}

Wagner, Roman J. V. ^{[1
,2
]}

Haak, Henrik ^{[3
]}

Meijer, Gerard ^{[3
]}

Wodtke, Alec M. ^{[1
,2
]}

Schaefer, Tim ^{[1
,2
]}

机构：

[1] Max Planck Inst Biophys Chem, Karl Friedrich Bonhoeffer Inst, D-37077 Gottingen, Germany

[2] Univ Gottingen, Inst Phys Chem, D-37077 Gottingen, Germany

[3] Max Planck Gesell, Fritz Haber Inst, Abt Mol Phys, D-14195 Berlin, Germany

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2013年 / 15卷 / 36期

基金：

美国国家科学基金会;

关键词：

SPECTROSCOPY; EXCITATION; MOLECULES; DEEXCITATION; ATOMS; SCATTERING; AU(111); SYSTEM; YIELDS;

D O I：

10.1039/c3cp52468j

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We have combined a Stark decelerator with a molecular beam-surface scattering setup to accurately measure the absolute electron emission yield, gamma, of CO (a(3)Pi) quenching at a Au(111) surface with quantum state resolution. We clearly observe an enhanced probability of electron emission when scattering vibrationally excited states of CO from the surface.

引用

页码：14951 / 14955

页数：5

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