Rhodium(III)-Catalyzed Oxidative C-H Functionalization of Azomethine Ylides

被引：118
|
作者：
Zhen, Wencui [1 ,2 ]
Wang, Fen [1 ]
Zhao, Miao [1 ]
Du, Zhengyin [2 ]
Li, Xingwei [1 ]
机构：
[1] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
[2] NW Normal Univ, Coll Chem & Chem Engn, Lanzhou 730070, Peoples R China
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 47期
关键词：
azomethines; C-H activation; olefination; oxidative coupling; rhodium; ONE-POT SYNTHESIS; ALPHA; BETA-UNSATURATED KETOXIMES; DIRECTING GROUP; BOND-CLEAVAGE; BENZOIC-ACIDS; ALKYNES; ACTIVATION; RH; BENZAMIDES; ROUTE;
D O I：
10.1002/anie.201207204
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Put it on a ring: A rhodium(III) complex can catalyze the oxidative coupling of azomethine imines with olefins, leading to the synthesis of 1,2-dihydrophthalazines, olefinated aldehydes, or fused pyridines, depending on the conditions used. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：11819 / 11823
页数：5
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