Formation of a σ-alkane Complex and a Molecular Rearrangement in the Solid-State: [Rh(Cyp2PCH2CH2PCyp2)(η2:η2-C7H12)][BAr4F]

被引：24

作者：

McKay, Alasdair I. ^{[1
]}

Kramer, Tobias ^{[2
]}

Rees, Nicholas H. ^{[1
]}

Thompson, Amber L. ^{[1
]}

Christensen, Kirsten E. ^{[1
]}

Macgregor, Stuart A. ^{[2
]}

Weller, Andrew S. ^{[1
]}

机构：

[1] Univ Oxford, Dept Chem, Mansfield Rd, Oxford OX1 3TA, England

[2] Heriot Watt Univ, Inst Chem Sci, Edinburgh EH14 4AS, Midlothian, Scotland

来源：

ORGANOMETALLICS | 2017年 / 36卷 / 01期

基金：

英国工程与自然科学研究理事会;

关键词：

H BOND ACTIVATION; NEUTRON-DIFFRACTION; NMR; PHOSPHINE;

D O I：

10.1021/acs.organomet.6b00645

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Addition of H-2 to the precursor [Rh(Cyp(2)PCH(2)CH(2)PCyp(2))(eta(2):eta(2)-C7H8)][BAr4F] gives the sigma-alkane complex [Rh(Cyp(2)PCH(2)CH(2)PCyp(2))(eta(2):eta(2)-C7H12)][BAr4F] by a single-crystal to single-crystal reaction, as characterized by X-ray crystallography, SSNMR spectroscopy, and periodic DFT. An unexpected rearrangement of the {Rh(L-2)}(+) fragment is revealed.

引用

页码：22 / 25

页数：4

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