Bulk and surface rheology of Aculyn™ 22 and Aculyn™ 33 polymeric solutions and kinetics of foam drainage

被引:24
作者
Bureiko, A.
Trybala, A. [1 ]
Huang, J. [1 ]
Kovalchuk, N. [1 ,2 ]
Starov, V. [1 ]
机构
[1] Univ Loughborough, Dept Chem Engn, Loughborough, Leics, England
[2] Inst Biocolloid Chem, Kiev, Ukraine
基金
英国工程与自然科学研究理事会;
关键词
Foam drainage; Bulk viscosity; Yield stress; Surface visco-elasticity; YIELD-STRESS; FLOW-THROUGH; STABILITY; POLYELECTROLYTE; BEHAVIOR;
D O I
10.1016/j.colsurfa.2013.05.072
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Experimental investigations of both bulk and surface rheology of solutions of commercially available polymers Aculyn (TM) 22 and Aculyn (TM) 33 in presence of sodium chloride are performed in a wide range of the polymer and salt concentrations. It is shown that the bulk viscosity and the surface viscoelastic modulus of solutions of both polymers increases with the increase of polymer concentration and the decrease of the salt concentration. Solutions of both polymers demonstrate very good foamability and form stable foams. Foam drainage is governed mainly by the bulk viscosity when the latter is in the range of 100-500 mPa s. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:268 / 275
页数:8
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