Recent Developments in Asymmetric Hetero-Diels-Alder Reactions of Dithioesters

被引：6

作者：

Dentel, Helene ^{[1
]}

Gulea, Mihaela ^{[1
]}

机构：

[1] ENSICAEN, LCMT, UMR CNRS 6507, INC3M,UCBN,FR 3038, F-14050 Caen, France

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2013年 / 188卷 / 04期

关键词：

Asymmetric hetero-Diels-Alder reaction; thia-Diels-Alder reaction; chiral dithioester; Cu(II); bis(oxazoline) complex; stereochemical models; HETERODIENOPHILES; BIS(OXAZOLINE); CONJUGATION;

D O I：

10.1080/10426507.2012.729113

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Recent studies dealing with asymmetric thia-Diels-Alder reactions of dithioesters as heterodienophiles are described. A diastereoselective version involving new chiral dithioesters and the first example of a catalytic enantioselective version are described. The absolute stereochemistry of the cycloadducts was assigned based on an X-ray structure and chemical correlation. In order to rationalize the sense of the chiral induction observed experimentally, stereochemical models for Cu(II)/BOX/dithioester complexes are proposed.

引用

页码：349 / 355

页数：7

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