Palladium-Catalyzed Aerobic Oxidative Coupling of Acyl Chlorides with Arylboronic Acids

被引：25

作者：

Chen, Jiuxi ^{[1
,3
]}

Peng, Yong ^{[1
]}

Liu, Miaochang ^{[1
]}

Ding, Jinchang ^{[1
,2
]}

Su, Weike ^{[3
]}

Wu, Huayue ^{[1
]}

机构：

[1] Wenzhou Univ, Coll Chem & Mat Engn, Wenzhou 325035, Peoples R China

[2] Wenzhou Vocat & Tech Coll, Coll Light Ind, Wenzhou 325035, Peoples R China

[3] Zhejiang Univ Technol, Key Lab Pharmaceut Engn, Minist Educ, Coll Pharmaceut Sci, Hangzhou 310014, Zhejiang, Peoples R China

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2012年 / 354卷 / 11-12期

基金：

中国国家自然科学基金;

关键词：

acyl chlorides; aryl benzoates; arylboronic acids; oxidative coupling; palladium; BAEYER-VILLIGER OXIDATION; PREPARING AROMATIC KETONES; SUZUKI-MIYAURA TYPE; CARBON TRIPLE BOND; CARBOXYLIC ANHYDRIDES; CONVENIENT METHOD; MOLECULAR-OXYGEN; ESTERS; ESTERIFICATION; EFFICIENT;

D O I：

10.1002/adsc.201100971

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The first example of a palladium-catalyzed aerobic oxidative coupling of acyl chlorides with arylboronic acids has been developed, leading to a wide range of aryl benzoates in good to excellent yields. This catalytic system shows broad functional group tolerance. Preliminary mechanistic experiments using deuterium labeling showed that the oxygen atom was derived from dioxygen.

引用

页码：2117 / 2122

页数：6

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