Joint analysis of absorption, magnetic circular dichroism, and resonance Raman spectra of CH3I excited in the a band

被引：16

作者：

Johnson, BR ^{[1
]}

Kinsey, JL ^{[1
]}

机构：

[1] RICE UNIV,RICE QUANTUM INST,HOUSTON,TX 77251

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1996年 / 100卷 / 49期

关键词：

D O I：

10.1021/jp9611030

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The broad structureless A band of CH3I has long been assigned to three overlapping transitions, although their relative strengths have been a subject of controversy. A new component analysis is made utilizing a simple dynamical model to rationalize the currently available absorption, magnetic circular dichroism, and resonance Raman excitation spectral data. Discrepancies between these and other CH3I photolysis experiments are examined.

引用

页码：18937 / 18943

页数：7

共 50 条

[1] ABINITIO POTENTIAL-ENERGY SURFACES AND TRAJECTORY STUDIES OF A-BAND PHOTODISSOCIATION DYNAMICS - CH3I STAR-]CH3+I AND CH3+I STAR [J].