Crystal structures of the chiral lithiosilanes [(Lis)-PhMe2SiLi•THF•(-)-sparteine] and [Ph2(NEt2)SiLi•(-)-sparteine]

被引：31

作者：

Strohmann, C ^{[1
]}

Däschlein, C ^{[1
]}

Auer, D ^{[1
]}

机构：

[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 03期

关键词：

D O I：

10.1021/ja057348k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The (-)-sparteine-coordinated lithiosilanes (Lis)-4 and 5 crystallize as monomers with coordination numbers of 4 and 3 on lithium and represent the first structurally characterized enantiopure lithiosilanes. Both systems are also monomeric in solution with Si-Li contacts detected by 29Si-7Li couplings in the 29Si NMR spectrum (for 5 even at room temperature). Copyright © 2006 American Chemical Society.

引用

页码：704 / 705

页数：2

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